氧化铝增韧氧化锆复合材料的性能及应用研究进展

doi:10.3969/j.issn.1001-1935.2025.05.014

耐火材料 ›› 2025, Vol. 59 ›› Issue (5): 450-454.DOI: 10.3969/j.issn.1001-1935.2025.05.014

氧化铝增韧氧化锆复合材料的性能及应用研究进展

丁贺玮

中国钢研科技集团有限公司北京 100081

收稿日期:2025-02-12 出版日期:2025-10-15 发布日期:2025-10-22
作者简介:丁贺玮:男,1982年生,硕士,工程师。E-mail:55814638@qq.com

Research progress on properties and applications of alumina-toughened zirconia composites

Ding Hewei

First author' address::Central Iron and Steel Research Institute Group,Beijing 100081,China

Received:2025-02-12 Online:2025-10-15 Published:2025-10-22

摘要/Abstract

摘要： 氧化铝增韧氧化锆(ATZ)材料结合了氧化铝和氧化锆2种陶瓷的优异性能,在工业领域具有广泛的应用前景。对ATZ材料中四方相氧化锆稳定性的影响因素进行了探讨,综述了ATZ材料的物理性能的提高方法,总结了其应用领域,最后对ATZ材料的发展前景进行了展望。

关键词: 氧化铝, 氧化锆, ATZ, 断裂韧性

Abstract: Alumina-toughened zirconia (ATZ) composites combine the excellent properties of both alumina and zirconia ceramics,and have broad application prospects in the industries field.The influencing factors of tetragonal zirconia stability in ATZ composites were discussed.The methods for improving the physical properties of ATZ composites and their application fields were summarized.Finally,the development prospect of ATZ composites was also expected.

Key words: alumina, zirconia, ATZ, fracture toughness

中图分类号:

TQ175

丁贺玮. 氧化铝增韧氧化锆复合材料的性能及应用研究进展[J]. 耐火材料, 2025, 59(5): 450-454.

Ding Hewei. Research progress on properties and applications of alumina-toughened zirconia composites[J]. Refractories, 2025, 59(5): 450-454.

参考文献

[1] 龙鑫,王驰原,邵长伟,等.先驱体转化氮化物高温透波陶瓷研究进展[J].硅酸盐学报,2024,52(9):2862-2874.
[2] 勾俊峰,杨鑫,张世宏,等.Cr₂O₃对Al₂O₃-Cr₂O₃涂层干滑动摩擦磨损行为的影响[J].中国表面工程,2022,35(2):176-186.
[3] 陈超,梁艳芬,梁天权,等.稀土复合掺杂ZrO₂陶瓷涂层抗Na₂SO₄+NaVO₂热腐蚀性能的研究进展[J].中国腐蚀与防护学报,2019,39(4):291-298.
[4] NORFAUZI T,HADZLEY A,AZLAN U,et al.Fabrication and machining performance of ceramic cutting tool based on the Al₂O₃-ZrO₂-Cr₂O₃ compositions[J].Journal of Materials Research and Technology,2019,8(6):5114-5123.
[5] REDDY D K S,BARMAVATU P,DAS M K,et al.Mechanical properties evaluation and microstructural analysis study of ceramic-coated IC engine cylinder liner[J].Materials Today:Proceedings,2023,76:518-523.
[6] 樊嘉显.高温合金熔炼用氧化铝坩埚制备与性能研究[D].西安:长安大学,2023.
[7] 徐铭骏,王子扬,高宇.车用涡轮增压器叶片材料的发展概述[J].沈阳工程学院学报(自然科学版),2019,15(4):373-376+384.
[8] 肖九梅.车用陶瓷及其应用解读[J].现代技术陶瓷,2011,32(3):44-50.
[9] 胡峰,侯龙轲,杨小乐,等.熔融沉积技术增材制造先进陶瓷材料研究现状和发展趋势[J].陶瓷学报,2024,45(5):849-864.
[10] 吕环祥.高可靠氧化铝陶瓷复合材料的设计、制备与性能研究[D].兰州:兰州理工大学,2023.
[11] 罗人豪,刘凯旋,刘志,等.氧化锆陶瓷低温老化研究进展[J].硅酸盐通报,2023,42(2):694-707.
[12] 张旭阳,王秀芳,万德田,等.氧化铝-氧化锆预应力陶瓷的抗钙镁铝硅酸盐腐蚀性能[J].硅酸盐学报,2024,52(12):3815-3823.
[13] 陈龙,梁新星,梁保青,等.梯度氧化锆/氧化铝陶瓷高温应力的结构依赖性及优化设计[J].材料导报,2025,39(12):71-77.
[14] 隋育栋.氧化锆增韧氧化铝复相陶瓷制备工艺的研究进展[J].科技创新与应用,2020,10(13):109-110.
[15] ZHENG T Q,WANG W,SUN J X,et al.Development and evaluation of Al₂O₃-ZrO₂ composite processed by digital light 3D printing[J].Ceramics International,2020,46(7):8682-8688.
[16] RITTIDECH A,SOMRIT R,TUNKASIRI T.Effect of adding Y₂O₃ on structural and mechanical properties of Al₂O₃-ZrO₂ ceramics[J].Ceramics International,2013,39:S433-S436.
[17] OKADA A.Automotive and industrial applications of structural ceramics in Japan[J].Journal of the European Ceramic Society,2008,28(5):1097-1104.
[18] GROSS C,BERGFELDT T,FRETWURST T,et al.Elemental analysis of commercial zirconia dental implants—Is “metal-free” devoid of metals?[J].Journal of the Mechanical Behavior of Biomedical Materials,2020,107:103759.
[19] 邓茂盛.氧化锆增韧氧化铝复合陶瓷制备及性能研究[J].陶瓷,2018(10):30-35.
[20] 朱琳琳,石双林,王洁.氧化锆增韧氧化铝陶瓷的研究进展[J].佛山陶瓷,2023,33(9):6-8.
[21] 丁凯东,李响,卢响,等.氧化锆增韧氧化铝陶瓷研究进展[J].材料工程,2025,53(4):75-90.
[22] SEQUEIRA S,FERNANDES M H,NEVES N,et al.Development and characterization of zirconia-alumina composites for orthopedic implants[J].Ceramics International,2017,43(1):693-703.
[23] NEVAREZ-RASCON A,AGUILAR-ELGUEZABAL A,ORRANTIA E,et al.On the wide range of mechanical properties of ZTA and ATZ based dental ceramic composites by varying the Al₂O₃ and ZrO₂ content[J].International Journal of Refractory Metals and Hard Materials,2009,27(6):962-970.
[24] PABST W,HAVRDA J,GREGOROVÁ E,et al.Alumina toughened zirconia made by room temperature extrusion of ceramic pastes[J].Ceramics Silikáty,2000,44:41-47.
[25] 黄红燕,邵忠财,王国营,等.溶胶共沉淀法制备氧化锆氧化铝复合粉体[J].材料研究学报,2008,22(3):246-250.
[26] BONIECKI M,SADOWSKI T,GOŁOBIEWSKI P,et al.Mechanical properties of alumina/zirconia composites[J].Ceramics International,2020,46(1):1033-1039.
[27] MEENA K L,SURESH VIDYASAGAR C,BENNY KARUNAKAR D.Mechanical and tribological properties of alumina toughened zirconia composites through conventional sintering and microwave sintering[J].Transactions of the Indian Institute of Metals,2020,73(7):1909-1923.
[28] DE AZA A H,CHEVALIER J,FANTOZZI G,et al.Crack growth resistance of alumina,zirconia and zirconia toughened alumina ceramics for joint prostheses[J].Biomaterials,2002,23(3):937-945.
[29] 刘文彬,赖泽标,伍玩秋,等.热等静压技术在透明陶瓷研究中的应用进展[J].现代技术陶瓷,2023,44(2):117-128.
[30] ZHU T B,XIE Z P,HAN Y,et al.A novel approach to improve flexural strength of Al₂O₃-20 wt% ZrO₂ composites by oscillatory pressure sintering[J].Journal of the American Ceramic Society,2018,101(4):1397-1401.
[31] ZHANG J,ZHU T B,SANG S B,et al.Optimization of microstructure and mechanical properties of oscillatory pressure sintered ZrO₂-Al₂O₃-SiC_p ceramics[J].Ceramics International,2022,48(6):7512-7521.
[32] 彭文法.氧化锆复合陶瓷的闪烧制备技术研究[D].东莞:东莞理工学院,2024.
[33] FAN J Y,YUAN Y,LI J S,et al.Densification and grain growth in oscillatory pressure sintering of alumina toughened zirconia ceramic composites[J].Journal of Alloys and Compounds,2020,845:155644.
[34] ABBAS M K G,RAMESH S,TASFY S F H,et al.Effect of microwave sintering on the properties of copper oxide doped alumina toughened zirconia (ATZ)[J].Journal of Materials Research and Technology,2023,25:1041-1054.
[35] GRABOWY M,WILK A,LACH R,et al.Hydrothermal aging of ATZ composites based on zirconia made of powders with different yttria content[J].Materials,2021,14(21):6418.
[36] 雷辉聪,谢志鹏,安迪.放电等离子烧结制备高强度及高硬度ATZ陶瓷[J].陶瓷学报,2022,43(3):455-461.
[37] GIL-FLORES L,SALVADOR M D,PENARANDA-FOIX F L,et al.Tribological and wear behaviour of alumina toughened zirconia nanocomposites obtained by pressureless rapid microwave sintering[J].Journal of the Mechanical Behavior of Biomedical Materials,2020,101:103415.
[38] MAJI A,CHOUBEY G.Microstructure and mechanical properties of alumina toughened zirconia (ATZ)[J].Materials Today:Proceedings,2018,5(2):7457-7465.
[39] TURON-VINAS M,ANGLADA M.Strength and fracture toughness of zirconia dental ceramics[J].Dental Materials,2018,34(3):365-375.
[40] GRABOWY M,DELIKHOVSKYI Y,WILK A,et al.Improvement of fracture toughness in dense ATZ composites prepared from zirconia powders with different yttria content[J].Composites:Theory and Practice,2021,21:161-168.
[41] 毛亚男,韩亚苓,王辰,等.压痕法测量ZrO₂/Al₂O₃陶瓷断裂韧性的研究[J].硅酸盐通报,2015,34(9):6.
[42] ZHANG F,LI L F,WANG E Z.Effect of micro-alumina content on mechanical properties of Al₂O₃/3Y-TZP composites[J].Ceramics International,2015,41(9):12417-12425.
[43] LEE D Y,KIM D J,KIM B Y.Influence of alumina particle size on fracture toughness of (Y,Nb)-TZP/Al₂O₃ composites[J].Journal of the European Ceramic Society,2002,22(13):2173-2179.
[44] KIHARA M,OGATA T,NAKAMURA K,et al.Effects of Al₂O₃ addition on mechanical properties and microstructures of Y-TZP[J].Journal of the Ceramic Society of Japan,1988,96(1114):646-653.
[45] LEONOV A.Effect of alumina nanofibers content on the microstructure and properties of ATZ composites fabricated by spark plasma sintering[J].Materials Today,2019,11:66-71.
[46] ABBAS M K G,RAMESH S,SARA LEE K Y,et al.Effects of sintering additives on the densification and properties of alumina-toughened zirconia ceramic composites[J].Ceramics International,2020,46(17):27539-27549.
[47] CHAIM R.Pressureless sintered ATZ and ZTA ceramic composites[J].Journal of Materials Science,1992,27(20):5597-5602.
[48] 王祖敏,胡章平,徐艺菲,等.一种氧化铝-氧化锆高温抗氧化复合层的制备方法:CN109160529A[P].2019-01-08.
[49] 薛召露,史云云,张世宏.一种共晶增韧抗烧结氧化铝/稀土掺杂氧化锆超高温热障涂层喷涂材料、制备方法及其应用:CN115418596B[P].2024-04-02.
[50] 高振昕,周宁生,王天仇,等.TiO₂在Al₂O₃-ZrO₂电熔料共晶体中的固溶行为[J].硅酸盐学报,2005,33(9):1145-1148.
[51] 廖建国.铝锆质骨料的显微结构对耐火材料的耐热震性的影响[J].国外耐火材料,2002,27(2):46-50.
[52] KERN F,GADOW R.Alumina toughened zirconia from yttria coated powders[J].Journal of the European Ceramic Society,2012,32(15):3911-3918.
[53] 朱东彬,宋艳军,梁金生,等.齿科用氧化锆陶瓷韧性研究进展[J].无机材料学报,2018,33(4):363-372.
[54] XU C,LIU Z Z,CHEN X,et al.Bone tissue engineering scaffold materials:Fundamentals,advances,and challenges[J].Chinese Chemical Letters,2024,35(2):109197.
[55] SIVASANKAR M V,CHINTA M L,SREENIVASA RAO P.Zirconia based composite scaffolds and their application in bone tissue engineering[J].International Journal of Biological Macromolecules,2024,265:130558.

氧化铝增韧氧化锆复合材料的性能及应用研究进展

Research progress on properties and applications of alumina-toughened zirconia composites

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	仲星宇, 赵世贤, 王刚, 李虹屿, 李凌锋, 梁鹏鹏, 田朋丹, 李红霞, 刘学智. Al(H₂PO₄)₃与SiO₂溶胶对氧化锆基涂层结构及性能的影响[J]. 耐火材料, 2025, 59(5): 386-390.
[2]	董雨晨, 张三华, 秦红彬, 李鹏鑫, 曹迎楠. 铝硅系耐火浇注料抗铝灰侵蚀性能研究[J]. 耐火材料, 2025, 59(5): 422-426.
[3]	张松婷, 赵世贤, 李虹屿, 李红霞, 司瑶晨, 李凌锋, 刘广华. 大气等离子喷涂纳米粉体热障涂层及其抗热震性能研究[J]. 耐火材料, 2025, 59(4): 289-296.
[4]	王冬冬, 余同暑, 赵洪波, 李红霞. 氧化钇外加量对镁稳氧化锆材料性能的影响[J]. 耐火材料, 2025, 59(3): 213-216.
[5]	孙家朐, 刘新, 丁璇, 吴锋, 罗旭东. 利用铁尾矿制备莫来石材料的研究[J]. 耐火材料, 2025, 59(1): 54-58.
[6]	高广泽, 张洪睿, 李建伟, 陈留刚. 活性氧化铝加入量对活性氧化镁结合刚玉-尖晶石浇注料性能的影响[J]. 耐火材料, 2024, 58(5): 419-423.
[7]	王江涛, 刘广华, 赵世贤, 邱海峰. 基于TRIZ理论解决氧化锆陶瓷制品烧成中的污染问题[J]. 耐火材料, 2024, 58(5): 445-447.
[8]	刘保侠, 张盟, 周绪强, 牛云松, 黄迪, 杨沁乾, 鲍泽斌, 朱圣龙. 高能等离子喷涂垂直裂纹氧化锆热障涂层工艺及结合性能研究[J]. 耐火材料, 2024, 58(4): 284-289.
[9]	任河, 佟天白, 刘梅, 王利娜, 范召东. 氧化铝气凝胶的耐温性能研究[J]. 耐火材料, 2024, 58(4): 297-301.
[10]	邓江, 刘学新, 李文, 张子翼, 员文杰. 氧化铝粒径和氧化锆粉外加量对氧化铝造粒粉性能的影响[J]. 耐火材料, 2024, 58(4): 307-313.
[11]	张会, 柴倩, 张红, 王艺兴, 郝晨曦, 王星雨. 氧化锆和氧化镧共掺杂对堇青石多孔陶瓷性能的影响[J]. 耐火材料, 2024, 58(2): 99-103.
[12]	王指正, 郭玉香, 杨晓东, 孙培凇. SiO₂-Al₂O₃复合气凝胶常压干燥制备技术研究进展[J]. 耐火材料, 2024, 58(2): 179-184.
[13]	夏玉婷, 杨文博, 饶羽彤, 聂锐杉, 姚远. 轻质高强莫来石浇注料的组分优化和性能增强[J]. 耐火材料, 2024, 58(1): 72-75.
[14]	梁新星, 高玉莹, 叶航, 马成良, 刘小钢, 范崇方, 徐恩霞. 玻璃窑炉用新型氧化锆基复合材料性能研究[J]. 耐火材料, 2023, 57(6): 518-522.
[15]	张涛, 谭清华, 冯志源, 王晗, 刘鹏程. 稳定剂种类对高纯氧化锆空心球制品性能的影响[J]. 耐火材料, 2023, 57(5): 397-401.