BN纳米管制备研究进展

doi:10.3969/j.issn.1001-1935.2021.04.016

耐火材料 ›› 2021, Vol. 55 ›› Issue (4): 338-347.DOI: 10.3969/j.issn.1001-1935.2021.04.016

BN纳米管制备研究进展

董骏峰(), 王洪红, 李孝建, 张海军()

武汉科技大学省部共建耐火材料与冶金国家重点实验室湖北武汉 430081

收稿日期:2020-09-05 出版日期:2021-08-15 发布日期:2021-08-22
通讯作者: 张海军,男,1970年生,教授。E-mail: zhanghaijun@wust.edu.cn
作者简介:董骏峰:男,1996年生,硕士研究生。E-mail: 1580997607@qq.com
基金资助:
国家自然科学基金面上项目(51872210);国家自然科学基金面上项目(51672194);湖北省自然科学基金创新群体项目(2017CFA004);湖北省教育厅高等学校优秀中青年科技创新团队计划(T201602)

Research progress on preparation of BN nanotubes

Dong Junfeng(), Wang Honghong, Li Xiaojian, Zhang Haijun()

The State Key Laboratory of Refractories and Metallurgy,Wuhan University of Science and Technology,Wuhan 430081,Hubei,China

Received:2020-09-05 Online:2021-08-15 Published:2021-08-22
Contact: Zhang Haijun

摘要/Abstract

摘要：

BN纳米管(BNNTs)是一种与碳纳米管相似的管状结构材料,因其优异的力学强度、高的热导率、良好的热稳定性及化学稳定性、超疏水性及优异的电绝缘性等性能,在冶金、化工、环境、催化及生物医学等领域具有广泛的应用前景。简要综述了电弧放电法、化学气相沉积法与球磨氮化反应法制备BNNTs的优缺点及影响因素,并对今后BNNTs的研究重点和方向进行了展望。

关键词: BN纳米管, 电弧放电法, 化学气相沉积法, 球磨氮化反应法

Abstract:

BN nanotubes (BNNTs) are tubular structural materials similar to carbon nanotubes.Owing to their excellent mechanical strength,high thermal conductivity,good thermal and chemical stability,super hydrophobicity and excellent electrical insulation,they have broad application prospects in the fields of metallurgy,chemical industry,environment,catalysis and biomedicine,etc.The advantages,shortcomings and influencing factors of arc discharge method,chemical vapor deposition method and ball milling nitridation reaction method to prepare BNNTs were briefly summarized.In addition,the future research focus and direction of BNNTs were proposed.

Key words: BN nanotubes, arc discharge method, chemical vapor deposition method, ball milling nitridation reaction method

中图分类号:

TQ126.2+9

董骏峰, 王洪红, 李孝建, 张海军. BN纳米管制备研究进展[J]. 耐火材料, 2021, 55(4): 338-347.

Dong Junfeng, Wang Honghong, Li Xiaojian, Zhang Haijun. Research progress on preparation of BN nanotubes[J]. Refractories, 2021, 55(4): 338-347.

图/表 4

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BN纳米管制备研究进展

Research progress on preparation of BN nanotubes

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参考文献 58

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制备方法	硼源	催化剂	反应气氛	优点	缺点	文献
电弧放电法	h-BN	无	He	可连续运行;不需要使用有机溶剂或危险性试剂	对仪器的要求较高且成本较高;产物的纯度较低且产量较低	[19]
	B	Co及Ni	N₂			[38]
	HfB₂	无	N₂			[39]
	h-BN及B	Ni	He-N₂			[40]
	h-BN	Ni及Y	Ar-N₂			[41]
CVD法	B₂O₃	Mg	NH₃	低成本且易于控制;产物的纯度较高且质量较高	需要使用化学试剂,易对环境造成污染;产物的产量较低	[42]
	B	α-Fe₂O₃	N₂-NH₃			[43]
	B	FeS及Fe₂O₃	N₂-NH₃			[2]
	B	MgO及Fe₂O₃	NH₃			[44]
	H₃BO₃	Fe(NO₃)₃·9H₂O	NH₃			[45]
	B	MgO及γ-Fe₂O₃	NH₃			[46]
	B	MgO及Fe₂O₃	NH₃			[47]
	MgB₂	MgB₂	NH₃			[48]
	B₂O₃	Li₃N	NH₃			[15]
	B	Co(NO₃)₂·6H₂O	NH₃			[49]
	B₂O₃和B	不锈钢基板	NH₃			[50]
球磨氮化反应法	B	无	N₂	工艺简单且成本低;产物的产量较高	需要使用化学试剂,易对环境造成污染;工艺耗时长;产物的纯度较低	[51]
	B	Li₂O	NH₃			[52]
	B	FeO及MgO	N₂			[53]
	B	Fe	N₂			[54]
	B、B₂O₃及MgB₂	MgB₂	NH₃			[55]
	B	不锈钢片	N₂			[56]
	B	Fe₃O₄	N₂			[57]
	B	Fe(NO₃)₃	N₂			[58]

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