Research progress on synthesis methods of CaZrO3 powder

doi:10.3969/j.issn.1001-1935.2025.06.014

Abstract

Abstract: CaZrO₃ is widely used in fields such as refractories,thermal barrier coatings,high mechanical strength ceramics,and biomedical materials owing to its high melting point,excellent thermal shock resistance,good mechanical properties,and low thermal conductivity.The recent research progress on the synthesis methods for CaZrO₃ powders was summarized,with a focus on analyzing the advantages and disadvantages of solid-state reaction,molten salt synthesis,and combustion synthesis methods.The CaZrO₃ powders obtained by different synthesis methods were compared.Future development direction of CaZrO₃ powders was prospected,including optimizing the precursor preparation process to lower the synthesis temperature and cost,deepening the theoretical research on synthesis mechanisms to improve the product quality and stability,enhancing the structural stability of zirconia crystals through raw material pretreatment,and expanding application fields via doping modification.

Key words: CaZrO₃, solid-state reaction method, molten salt method, combustion synthesis method

摘要： CaZrO₃材料凭借其高熔点、优异的抗热震性、良好的力学性能与低导热特性,被广泛应用于耐火材料、热障涂层、高机械强度陶瓷及生物医学材料等领域。综述了近年来CaZrO₃粉体的合成方法研究进展,重点分析了固相反应法、熔盐法和燃烧法的优缺点,并对比了不同合成方法所得到的CaZrO₃粉体。展望了CaZrO₃粉体未来的发展方向,包括优化前驱体制备工艺以降低合成温度和成本,深化合成理论研究以提高产品质量与稳定性,通过原料预处理增强氧化锆晶体结构稳定性,以及通过掺杂改性拓展其应用领域等。

关键词: CaZrO₃, 固相反应法, 熔盐法, 燃烧法

CLC Number:

TQ175

Zhao Xinxin, Xu Qing, Huang Xiaoyang, Peng Jinqi, Duan Hongjuan , Zhang Haijun, Li Shaoping. Research progress on synthesis methods of CaZrO₃ powder[J]. Refractories, 2025, 59(6): 530-535.

赵鑫鑫, 许晴, 黄潇阳, 彭金琦, 段红娟, 张海军, 李少平. CaZrO₃粉体的合成方法研究进展[J]. 耐火材料, 2025, 59(6): 530-535.

References

[1] 方平.高近红外反射无机颜料的溶液燃烧法制备及其性能研究[D].南昌:南昌大学,2023.
[2] 房永超.锆酸镧基陶瓷热防护涂层的多元稀土高熵化改性研究[D].哈尔滨:哈尔滨工程大学,2022.
[3] 何桥.锆酸钙薄膜电容特性的研究[D].成都:四川大学,2021.
[4] 刘文斐.钙钛矿高熵氧化物粉体和陶瓷的制备及性能研究[D].西安:长安大学,2023.
[5] 张广宇,王榕林,刘一帆,等.CaZrO₃的合成及其高温化学稳定性研究[J].耐火材料,2019,53(4):288-293.
[6] 丁语珊.固相烧结法制备Ti掺杂CuGaS₂中间带材料及其光电特性研究[D].呼和浩特:内蒙古大学,2021.
[7] SHAN K,ZHAI F R,YI Z Z,et al.Mixed conductivity and the conduction mechanism of the orthorhombic CaZrO₃ based materials[J].Surfaces and Interfaces,2021,23:100905.
[8] 刘建,孙德业,张增奇,等.溶液浓缩辅助固相法合成磷酸锰铁锂正极材料[J].电源技术,2019,43(3):365-367.
[9] 李若可,孟俊杰,潘志东,等.软机械力化学辅助固相法合成铈掺杂钇铝石榴石荧光粉及其发光性能[J].硅酸盐学报,2015,43(12):1783-1789.
[10] HUERTA-RIVERA C A,BERNAL R,CRUZ-VÁZQUEZ C,et al.Beta particle excited thermoluminescence of CaZrO₃ phosphors synthesized by solid state reaction[J].Applied Radiation and Isotopes,2021,168:109519.
[11] PENG J Z,LI H P,REN D S,et al.Electrical properties of a solid electrolyte based on In₂O₃-doped CaZrO₃ prepared by high-pressure sintering[J].International Journal of Electrochemical Science,2020,15(6):5449-5455.
[12] 黄孝华,付长翼,胡紫.非水溶胶-凝胶法制备氧化锆陶瓷膜的技术研究[J].中国陶瓷,2016,52(9):29-32.
[13] CATAURO M,BOLLINO F,TRANQUILLO E,et al.Morphological and thermal characterization of zirconia/hydroxyapatite composites prepared via Sol-gel for biomedical applications[J].Ceramics International,2019,45(2):2835-2845.
[14] 张蒙.溶胶凝胶法制备α-Al₂O₃粉体的研究[D].重庆:重庆理工大学,2021.
[15] 计强.浸渍法和溶胶-凝胶法超疏水棉织物涂层的制备及其油水分离性能[D].广州:华南理工大学,2018.
[16] AZEEM P A,EVANGELINE B,HARANATH D,et al.Investigation of lanthanum-sensitized CaZrO₃ blue nanophosphors for white light-emitting diode applications[J].Luminescence,2021,36(2):481-488.
[17] FENG Q N,HU Y C,LIU D,et al.Incorporation of CaZrO₃ into calcium-based heat carriers for efficient solar thermochemical energy storage[J].Solar Energy Materials and Solar Cells,2024,266:112700.
[18] 张伟鹏.溶胶-凝胶法合成Al₂O₃-2SiO₂粉体及其应用研究[D].南宁:广西大学,2008.
[19] 陈萌.溶胶-凝胶法制备ZrSiO₄包覆ZrB₂粉体及其抗氧化性研究[D].武汉:武汉理工大学,2017.
[20] 刘松浩.溶胶-凝胶法制备SiO₂杂化环氧树脂及其胶接性能研究[D].哈尔滨:黑龙江省科学院石油化学研究院,2022.
[21] TOMAI T,NAKAYASU Y,OKAMURA Y,et al.Bottom-up synthesis of graphene via hydrothermal cathodic reduction[J].Carbon,2020,158:131-136.
[22] 李沛垚.水热法制备锂离子电池三元正极材料及其性能研究[D].长沙:中南大学,2023.
[23] MANJUNATHA S,MANJUNATHA H C,VIDYA Y S,et al.Microwave assisted synthesis,photoluminescence and X-ray/gamma ray absoprtion properties of red CaZrO₃:Eu³⁺ perovskite[J].Journal of Solid State Chemistry,2022,313:123245.
[24] RUIZ-JORGE F,BENÍTEZ A,FERNÁNDEZ-GARCÍA S,et al.Effect of fast heating and cooling in the hydrothermal synthesis on LiFePO₄ microparticles[J].Industrial & Engineering Chemistry Research,2020,59(19):9318-9327.
[25] SHEN C Q,XU H,LIU L,et al.Facile one-step dynamic hydrothermal synthesis of spinel LiMn₂O₄/carbon nanotubes composite as cathode material for lithium-ion batteries[J].Materials,2019,12(24):4123.
[26] SAKTI L O M,WIJAYA K,TRISUNARYANTI W,et al.The synthesis of SO₄/ZrO₂ and Zr/CaO catalysts via hydrothermal treatment and their application for conversion of low-grade coconut oil into biodiesel[J].Journal of Environmental Chemical Engineering,2020,8(5):104205.
[27] COSTA M W,GERMANO B A J,DE-OLIVEIRA-ROCHA K,et al.Photoluminescence of Eu³⁺-doped CaZrO₃ red-emitting phosphors synthesized via microwave-assisted hydrothermal method[J].Materials Today Communications,2020,24:100966.
[28] MACEDO W D,SOUZA A E,SANTOS G T A,et al.Microwave-assisted hydrothermal synthesis followed by heat treatment:A new route to obtain CaZrO₃[J].Ceramics International,2018,44(1):953-958.
[29] ALMUQRIN A H,SAYYED M I.Radiation shielding characterizations and investigation of TeO₂-WO₃-Bi₂O₃ and TeO₂-WO₃-PbO glasses[J].Applied Physics A,2021,127(3):190.
[30] 任洁.水热法制备高熵陶瓷粉体及其光反射性能研究[D].大连:大连交通大学,2024.
[31] 李欣怡.水热法可控生长PbZr_0.52Ti_0.48O₃纳米晶体及其生长机理研究[D].武汉:武汉理工大学,2020.
[32] STRACHAN J,MASTERS A F,MASCHMEYER T.Critical review:Hydrothermal synthesis of 1T-MoS₂—an important route to a promising material[J].Journal of Materials Chemistry A,2021,9(15):9451-9461.
[33] 梁雅璐.超重力共沉淀法制备钐掺杂钛酸钡及性能研究[D].太原:中北大学,2023.
[34] NAKAYA Y,HIRAYAMA J,YAMAZOE S,et al.Single-atom Pt in intermetallics as an ultrastable and selective catalyst for propane dehydrogenation[J].Nature Communications,2020,11(1):2838.
[35] WAHSH M M S,GABER A A,OTHMAN A G M.Sintering behavior and technological properties of nano-cubic zirconia/calcium zirconate ceramic composites[J].Journal of the Korean Ceramic Society,2020,57(2):161-166.
[36] XU T T,SU Y,SHI T,et al.Improving hydration resistance of MgO-CaO ceramics by in situ synthesized CaZrO₃ coatings prepared using a non-hydrolytic sol[J].Ceramics International,2021,47(2):2165-2171.
[37] HAN P W,LV H X,LI X G,et al.Perovskite CaZrO₃ for efficient ozonation treatment of organic pollutants in wastewater[J].Catalysis Science & Technology,2021,11(11):3697-3705.
[38] HAN P W,LI X N,JIN C Y,et al.Cation deviated stoichiometry Ca_1.1ZrO₃ perovskite as an efficient ozonation catalyst for m-cresol wastewater degradation[J].Chemical Engineering Journal,2022,429:132218.
[39] 卢晶晶.短碳链醇脱氢合成醛(酮)的催化剂制备与应用研究[D].沈阳:沈阳工业大学,2022.
[40] 马国轩.共沉淀法制备磷酸猛铁锂及其电化学性能研究[D].青岛:山东科技大学,2020.
[41] 王婷.熔盐法制备碳基复合材料及其析氢析氧性能的研究[D].西安:陕西科技大学,2023.
[42] HU J W,WU D Y,ZHU C,et al.Melt-salt-assisted direct transformation of solid oxide into atomically dispersed FeN₄ sites on nitrogen-doped porous carbon[J].Nano Energy,2020,72:104670.
[43] SHAKOURY R,ARMAN A,TĂLU S,et al.Stereometric analysis of TiO₂ thin films deposited by electron beam ion assisted[J].Optical and Quantum Electronics,2020,52(5):270.
[44] LIU X Y,KHANGKHAMANO M,ZHANG L,et al.Molten salt mediated in situ template formation of reticulated foams of complex oxides and carbides[J].Ceramics International,2024,50(4):7198-7201.
[45] KATYAYAN S,AGRAWAL S.Study of optical behaviour of Eu³⁺ and Tb³⁺ doped zirconate perovskite phosphors prepared by molten salt technique[J].Optical and Quantum Electronics,2019,52(1):18.
[46] 刘芮嘉.熔盐法制备钒的碳/氮化物及其电化学性能研究[D].合肥:中国科学技术大学,2023.
[47] 段小川.基于离子液体的液相法制备无机纳米材料及性能研究[D].天津:南开大学,2013.
[48] 时雪钊.几种纳米材料的电化学法及液相法制备、分析与表征[D].兰州:兰州大学,2011.
[49] 罗童.溶胶凝胶燃烧法钙基CO₂吸附剂的制备条件优化研究[D].武汉:华中科技大学,2021.
[50] 裴力.基于“燃烧法” 的高性能苯并噁嗪树脂及碳纤维复合材料的制备与研究[D].太原:中北大学,2021.
[51] SHARMA K.Performance and emission characteristics of the thermal barrier coated SI engine by adding argon inert gas to intake mixture[J].Journal of Advanced Research,2015,6(6):819-826.
[52] 宫红,吴静,赵旭光,等.微波辅助燃烧法合成LaMgB₅O₁₀晶体[J].稀有金属与硬质合金,2021,49(6):37-41+46.
[53] HEIDARI M,MOUSAVI S B,RAHMANI F,et al.The novel carbon nanotube-assisted development of highly porous CaZrO₃-CaO xerogel with boosted sorption activity towards high-temperature cyclic CO₂ capture[J].Energy Conversion and Management,2022,274:116461.
[54] VENUGOPAL M,KUMAR H P,SATHEESH R,et al.Effect of annealing temperature in the emission properties of nanocrystalline CaZr_0.9Sm_xDy_0.1-xO₃ systems prepared via self-propagating combustion synthesis[J].Physics Letters A,2020,384(14):126280.
[55] DUNYUSHKINA L A,KHALIULLINA A S,MESHCHERSKIKH A N,et al.Sintering and conductivity of Sc-doped CaZrO₃ with Fe₂O₃ as a sintering aid[J].Ceramics International,2021,47(8):10565-10573.
[56] JAFARI F M,JALALI M R,KARIMI L,et al.UV excited thermoluminescence and kinetic analysis of CaZrO₃:XCe³⁺ phosphors synthesized by Sol-gel combustion method[J].Optical and Quantum Electronics,2023,55(14):1257.
[57] PRASANNA K S G,HARI K R,KOTTAM N,et al.Understanding the photoluminescence behaviour in nano CaZrO₃:Eu³⁺ pigments by judd-ofelt intensity parameters[J].Dyes and Pigments,2018,150:306-314.
[58] 石佳佳.燃烧合成制备含碳铝酸钙粉体及其机理研究[D].西安:西安建筑科技大学,2018.

Research progress on synthesis methods of CaZrO₃ powder

CaZrO₃粉体的合成方法研究进展

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 9

Recommended Articles

Metrics

Comments

[1]	Dong Zeming, Dong Zeguang, Wang Shuxing, Liu Zhaoyang. Preparation of MgB₂O₅ whiskers from reverse flotation magnesite tailings [J]. Refractories, 2025, 59(3): 185-191.
[2]	Wang Xinyue, Xu Qing, Zhu Xinxin, Zhou Ruiqi, Duan Hongjuan, Zhang Haijun, Li Shaoping. Synthesis of porous MgAl₂O₄ fibers by solid-state reaction [J]. Refractories, 2024, 58(3): 190-194.
[3]	Liu Zhongfei, Wu Feng, Li Xinwei, Liang Xiaocheng, Luo Xudong, Qian Guohua. Corrosion mechanisms of CaO to MgAl₂O₄ materials and ZrO₂-MgAl₂O₄ materials [J]. Refractories, 2024, 58(3): 199-203.
[4]	Liang Xiaocheng, Feng Yu, Liu Zhongfei, Luo Xudong, Huang Min, Wu Feng. Effect of pre-synthesized CaZrO₃ on properties of magnesia-zirconia refractories [J]. Refractories, 2024, 58(3): 213-217.
[5]	Wang Sen, Liang Feng, Wang Xiaohan, Gu Haohui, Wu Shuaibing, Lyu Gongye, Zhang Haijun. Synthesis and hydration resistance of α-Si₃N₄-AlN composite powder by molten salt method [J]. Refractories, 2023, 57(1): 27-30.
[6]	Su Yuxi, Li Xinwei, Wu Feng, Gao Yongjun, Luo Xudong, Feng Yu, Chen Weimin. Effect of SiO₂ particle size and reaction temperature on synthesis of mullite whiskers by molten salt method [J]. Refractories, 2022, 56(4): 342-345.
[7]	Wang Shaoyang, Qi Xin, Luo Xudong, Jing Changsheng, Li Zhen, Wang Peng. Effect of molten salt types on synthesis of forsterite by molten salt method [J]. Refractories, 2022, 56(3): 185-188.
[8]	Kang Guowei, Liu Miaowei, Yang Yafeng, Liu Xinhong, . Preparation of calcium hexaaluminate porous materials by molten salt pore-forming method [J]. Refractories, 2021, 55(5): 448-451.
[9]	Si Chaowei, Lang Jiefu, You Jiegang, Tan Wendong, She Yiming. Effect of four molten salts on synthesis of hercynite powder by molten salt method [J]. Refractories, 2021, 55(1): 77-80.