稀土锆酸盐热障涂层材料的研究进展

doi:10.3969/j.issn.1001-1935.2021.03.017

耐火材料 ›› 2021, Vol. 55 ›› Issue (3): 258-263.DOI: 10.3969/j.issn.1001-1935.2021.03.017

稀土锆酸盐热障涂层材料的研究进展

李迪(), 李享成(), 朱颖丽, 陈平安, 朱伯铨

武汉科技大学省部共建耐火材料与冶金国家重点实验室湖北武汉 430081

收稿日期:2020-08-11 出版日期:2021-06-15 发布日期:2021-06-24
通讯作者: 李享成,男,1978年生,博士,副教授。E-mail: lixiangcheng@wust.edu.cn
作者简介:李迪:男,1996年生,硕士研究生。E-mail: 13577490907@163.com
基金资助:
国家自然科学基金资助项目(51972242)

Research progress of rare-earth zirconate thermal barrier coatings

Li Di(), Li Xiangcheng(), Zhu Yingli, Chen Ping’an, Zhu Boquan

The State Key Laboratory of Refractories and Metallurgy,Wuhan University of Science and Technology,Wuhan 430081,Hubei,China

Received:2020-08-11 Online:2021-06-15 Published:2021-06-24
Contact: Li Xiangcheng

摘要/Abstract

摘要：

稀土锆酸盐热障涂层材料具有耐高温、抗烧结、低导热、高温相结构稳定和抗腐蚀性能好等优点,被认为是最具有潜力的新型高温热障涂层材料体系之一。概述了目前关于这种热障涂层材料体系的晶体结构、物理性能、力学性能、抗热震性以及热腐蚀性等的研究进展,并进一步展望了稀土锆酸盐热障涂层材料的发展方向。

关键词: 稀土锆酸盐, 热障涂层, 晶体结构, 热腐蚀性

Abstract:

The rare-earth zirconates were proposed as one of the most promising high-temperature thermal barrier materials as a result of a combination of many excellent properties,such as high temperature resistance,anti-sintering,low thermal conductivity,stable high-temperature phase structure and good corrosion resistance.The research progress of the crystal structure,physical properties,mechanical properties,thermal shock resistance and thermal corrosion resistance of the thermal barrier coating system was reviewed,and the development direction of these materials in the future was further prospected.

Key words: rare-earth zirconates, thermal barrier coating, crystal structure, thermal corrosion properties

中图分类号:

TB321

李迪, 李享成, 朱颖丽, 陈平安, 朱伯铨. 稀土锆酸盐热障涂层材料的研究进展[J]. 耐火材料, 2021, 55(3): 258-263.

Li Di, Li Xiangcheng, Zhu Yingli, Chen Ping’an, Zhu Boquan. Research progress of rare-earth zirconate thermal barrier coatings[J]. Refractories, 2021, 55(3): 258-263.

图/表 3

参考文献 45

[1]	MILLER R A. Thermal barrier coatings for aircraft engines:history and directions[J]. J Therm Spray Technol, 1997,6(1):35-42. DOI URL
[2]	孙方红, 马壮, 刘应瑞, 等. 等离子喷涂陶瓷涂层降低孔隙率的研究进展[J]. 硅酸盐通报, 2013,32(11):2274-2280.
[3]	CAO X Q, VASSEN R, JUNGEN W, et al. Thermal stability of lanthanum zirconate plasma-sprayed coating[J]. J Am Ceram Soc, 2001,84(9):2086-2090. DOI URL
[4]	张小锋, 周克崧, 宋进兵, 等. 黏结层粗糙度对热障涂层高温氧化及力学性能的影响[J]. 硅酸盐学报, 2013,41(12):1674-1678.
[5]	VASSEN R, CAO X Q, TIETZ F, et al. Zirconates as new materials for thermal barrier coatings[J]. J Am Ceram Soc, 2000,83(8):2023-2028. DOI URL
[6]	SICKAFUS K E, MINERVINI L, GRIMES R W, et al. Radiation tolerance of complex oxides[J]. Science, 2000,289(5480):748-751. DOI URL
[7]	刘占国. A₂Zr₂O₇型稀土锆酸盐材料的组织结构与物理性能研究[D]. 哈尔滨:哈尔滨工业大学, 2009.
[8]	MICHEL D, PEREZYJ M, COLLONGUES R. Etude de la transformation ordre-desordre de la structure fluorite a la structure pyrochlore pour des phases (1-x)ZrO₂-xLn₂O₃[J]. Mater Res Bull, 1974,9(11):1457-1468. DOI URL
[9]	HARVEY E J, WHITTLE K R, LUMPKIN G R, et al. Solid solubilities of (La,Nd)₂(Zr,Ti)₂O₇ phases deduced by neutron diffraction[J]. J Solid State Chem, 2004,178(3):800-810. DOI URL
[10]	MANDAL B P, BANERJI A, SATHE V, et al. Order-disorder transition in Nd₂-_yGd_yZr₂O₇ pyrochlore solid solution:an X-ray diffraction and raman spectroscopic study[J]. J Solid State Chem, 2007,180(10):2643-2648. DOI URL
[11]	WHITTLE K R, CRANSWICK L M D, REDFERN S A T, et al. Lanthanum pyrochlores and the effect of yttrium addition in the systems La₂-_xY_xZr₂O₇ and La₂-_xY_xHf₂O₇[J]. J Solid State Chem, 2009,182(3):442-450. DOI URL
[12]	CAO X Q, VASSEN R, STOEVER D. Ceramic materials for thermal barrier coatings[J]. J Eur Ceram Soc, 2004,24(1):1-10. DOI URL
[13]	SURESH G, SEENIVASAN G, KRISHNAISH P, et al. Investigation of the thermal conductivity of selected compounds of gadolinium and lanthanum.[J]. J Nucl Mater, 1997,249:259-261. DOI URL
[14]	XU C H, JIN H Y, ZHANG Q F, et al. A novel Co-ions complexation method to synthesize pyrochlore La₂Zr₂O₇[J]. J Eur Ceram Soc, 2017,37(8):2871-2876. DOI URL
[15]	LEHMANN H, PIETZER D, PRACHT G, et al. Thermal conductivity and thermal expansion coefficients of the lanthanum rare-earth-element zirconate system[J]. J Am Ceram Soc, 2003,86(8):1338-1344. DOI URL
[16]	WU J, WEI X Z, PADTURE N P, et al. Low-thermal-conductivity rare-earth zirconates for potential thermal barrier coating applications[J]. J Am Ceram Soc, 2002,85(12):3031-3035. DOI URL
[17]	SURESH G, SEENIVASAN G, KRISHNAIAH M V, et al. Investigation of the thermal conductivity of selected compounds of lanthanum,samarium and europium[J]. J Alloys Compd, 1998,269(1):9-12.
[18]	SCHELLING P K, PHILLPOT S R, GRIMES R W. Optimum pyrochlore compositions for low thermal conductivity[J]. Philos Mag Lett, 2004,84(2):127-137. DOI URL
[19]	XU Q, PAN W, WANG J D, et al. Rare-earth zirconate ceramics with fluorite structure for thermal barrier coatings[J]. J Am Ceram Soc, 2006,89(1):340-342. DOI URL
[20]	XU Q, PAN W, WANG J D, et al. Preparation and thermophysical properties of Dy₂Zr₂O₇ ceramic for thermal barrier coatings[J]. Mater Lett, 2005,59(22):2804-2807. DOI URL
[21]	XIANG J Y, CHEN S H, HUANG J H, et al. Phase structure and thermophysical properties of co-doped La₂Zr₂O₇ ceramics for thermal barrier coatings[J]. Ceram Int, 2012,38(5):3607-3612. DOI URL
[22]	ZHU D M, MILLER R A. Thermal conductivity and elastic modulus evolution of thermal barrier coatings under high heat flux conditions[J]. J Therm Spray Technol, 2000,9(2):175-180. DOI URL
[23]	孙现凯, 陈玉峰, 王广海, 等. 大气等离子喷涂Sm₂Zr₂O₇热障涂层的隔热性能研究[J]. 稀有金属材料与工程, 2015,44(S1):735-739.
[24]	ZHOU H M, YI D Q, YU Z M, et al. Preparation and thermophysical properties of CeO₂ doped La₂Zr₂O₇ ceramic for thermal barrier coatings[J]. J Alloys Compd,2007, 2007,438(1-2):217-221.
[25]	ZHU R B, ZOU J P, WANG D P, et al. X-ray diffractional,spectroscopic and thermo-physical properties analyses on Eu-doped lanthanum zirconate ceramic for thermal barrier coatings[J]. J Alloys Compd, 2018,746:62-67. DOI URL
[26]	GUO L, GUO H B, PENG H, et al. Thermophysical properties of Yb₂O₃ doped Gd₂Zr₂O₇ and thermal cycling durability of (Gd_0.9Yb_0.1)₂Zr₂O₇/YSZ thermal barrier coatings[J]. J Eur Ceram Soc, 2014,34(5):1255-1263. DOI URL
[27]	MA L, MA W M, SUN X D, et al. Microstructures and mechanical properties of Gd₂Zr₂O₇/ZrO₂(3Y) ceramics[J]. J Alloys Compd, 2015,644:416-422. DOI URL
[28]	LEE K S, JUNG K I, HEO Y S, et al. Thermal and mechanical properties of sintered bodies and EB-PVD layers of Y₂O₃ added Gd₂Zr₂O₇ ceramics for thermal barrier coatings[J]. J Alloys Compd, 2010,507(2):448-455. DOI URL
[29]	WU H X, MA Z, LIU L, et al. Thermal cycling behavior and bonding strength of single-ceramic-layer Sm₂Zr₂O₇ and double-ceramic-layer Sm₂Zr₂O₇/8YSZ thermal barrier coatings deposited by atmospheric plasma spraying[J]. Ceram Int, 2016,42(11):12922-12927. DOI URL
[30]	JIN G, FANG Y C, CUI X F, et al. Effect of YSZ fibers and carbon nanotubes on bonding strength and thermal cycling lifetime of YSZ-La₂Zr₂O₇ thermal barrier coatings[J]. Surf Coat Technol, 2020,397:125986-125996. DOI URL
[31]	ISLAM A, KUMAR K, PANDEY K K, et al. Exceptionally high fracture toughness of carbon nanotube reinforced plasma sprayed lanthanum zirconate coatings[J]. J Alloys Compd, 2019,777:1133-1144. DOI URL
[32]	XU Z H, HE L M, CHEN X L, et al. Thermal cycling behavior of La₂Zr₂O₇ coating with the addition of Y₂O₃ by EB-PVD[J]. J Alloys Compd, 2010,508(1):85-93. DOI URL
[33]	LIU Z G, ZHANG W H, OUYANG J H, et al. Novel thermal barrier coatings based on rare-earth zirconates/YSZ double-ceramic-layer system deposited by plasma spraying[J]. J Alloys Compd, 2015,647:438-444. DOI URL
[34]	LASHMI P G, MAJITHIA S, SHWETHA V, et al. Improved hot corrosion resistance of plasma sprayed YSZ/Gd₂Zr₂O₇ thermal barrier coating over single layer YSZ[J]. Mater Charact, 2019,147:199-206. DOI URL
[35]	SCHULZ U, NOWOTNIK A, KUNKEL S, et al. Effect of processing and interface on the durability of single and bilayer 7YSZ/gadolinium zirconate EB-PVD thermal barrier coatings[J]. Surf Coat Technol, 2020,381:125107-125116. DOI URL
[36]	MAHADE S, CURRY N, BJÖRKLUND S, et al. Thermal conductivity and thermal cyclic fatigue of multilayered Gd₂Zr₂O₇/YSZ thermal barrier coatings processed by suspension plasma spray[J]. Surf Coat Technol, 2015,283:329-336. DOI URL
[37]	MAHADE S, CURRY N, BJÖRKLUND S, et al. Failure analysis of Gd₂Zr₂O₇/YSZ multi-layered thermal barrier coatings subjected to thermal cyclic fatigue[J]. J Alloys Compd, 2016,689:1011-1019. DOI URL
[38]	ZHANG H L, GUO L, MA Y, et al. Thermal cycling behavior of (Gd_0.9Yb_0.1)₂Zr₂O₇/8YSZ gradient thermal barrier coatings deposited on Hf-doped NiAl bond coat by EB-PVD[J]. Surf Coat Technol, 2014,258:950-955. DOI URL
[39]	WANG L, WANG Y, SUN X G, et al. Thermal shock behavior of 8YSZ and double-ceramic-layer La₂Zr₂O₇/8YSZ thermal barrier coatings fabricated by atmospheric plasma spraying[J]. Ceram Int, 2012,38(5):3595-3606. DOI URL
[40]	WANG C H, WANG Y, FAN S, et al. Optimized functionally graded La₂Zr₂O₇/8YSZ thermal barrier coatings fabricated by suspension plasma spraying[J]. J Alloys Compd, 2015,649:1182-1190. DOI URL
[41]	XU Z H, HE L M, MU R D, et al. Hot corrosion behavior of La₂Zr₂O₇ with the addition of Y₂O₃ thermal barrier coatings in contacts with vanadate-sulfate salts[J]. J Alloys Compd, 2010,504(2):382-385. DOI URL
[42]	BAHAMIRIAN M, HADAVI S M M, FARVIZI M, et al. Enhancement of hot corrosion resistance of thermal barrier coatings by using nanostructured Gd₂Zr₂O₇ coating[J]. Surf Coat Technol, 2019,360:1-12. DOI URL
[43]	LI M Z, CHENG Y X, GUO L, et al. Preparation of nanostructured Gd₂Zr₂O₇-LaPO₄ thermal barrier coatings and their calcium-magnesium-alumina-silicate (CMAS) resistance[J]. J Eur Ceram Soc, 2017,37(10):3425-3434. DOI URL
[44]	ZHANG C G, ZHAO J L, YANG L, et al. Preparation and corrosion resistance of nonstoichiometric lanthanum zirconate coatings[J]. J Eur Ceram Soc, 2020,40(8):3122-3128. DOI URL
[45]	WANG R, DONG T S, WANG H D, et al. CMAS corrosion resistance in high temperature and rainwater environment of double-layer thermal barrier coatings odified by rare earth[J]. Ceram Int, 2019,45(14):17409-17419. DOI URL

原子	烧绿石结构 (Fd3m)	萤石结构 (Fm3m)	缺陷型萤石结构 (Fm3m)
L	16d	4a	16c或16d
Zr	16c	4a	16c或16d
O	48f	8c	48f、8a或8b
O'	8b	—	48f、8a或8b
Vo	8a	—	48f、8a或8b

原子	烧绿石结构 (Fd3m)	萤石结构 (Fm3m)	缺陷型萤石结构 (Fm3m)
L	16d	4a	16c或16d
Zr	16c	4a	16c或16d
O	48f	8c	48f、8a或8b
O'	8b	—	48f、8a或8b
Vo	8a	—	48f、8a或8b

材料	热导率/(W·m^-1·K^-1)	热膨胀系数×10⁶/K^-1
La₂Zr₂O₇	1.56(1 000 ℃)^[12]	9.1(1 000 ℃)^[12]
	1.30(1 100 ℃)^[13]	—
	1.15(1 450 ℃)^[14]	—
Nd₂Zr₂O₇	1.25(800 ℃)^[15]	9.5(800 ℃)^[15]
Sm₂Zr₂O₇	1.6(700 ℃)^[16]	—
Sm₂Zr₂O₇	1.5(1 100 ℃)^[17]	10.8(1 200 ℃)^[18]
Eu₂Zr₂O₇	1.60(1 100 ℃)^[17]	—
Gd₂Zr₂O₇	1.91(1 200 ℃)^[18]	11.6(1 200 ℃)^[18]
Dy₂Zr₂O₇	1.34(800 ℃)^[19]	11.1(1 200 ℃)^[20]
Er₂Zr₂O₇	1.49(800 ℃)^[19]	—
Yb₂Zr₂O₇	1.58(800 ℃)^[19]	—

材料	热导率/(W·m^-1·K^-1)	热膨胀系数×10⁶/K^-1
La₂Zr₂O₇	1.56(1 000 ℃)^[12]	9.1(1 000 ℃)^[12]
	1.30(1 100 ℃)^[13]	—
	1.15(1 450 ℃)^[14]	—
Nd₂Zr₂O₇	1.25(800 ℃)^[15]	9.5(800 ℃)^[15]
Sm₂Zr₂O₇	1.6(700 ℃)^[16]	—
Sm₂Zr₂O₇	1.5(1 100 ℃)^[17]	10.8(1 200 ℃)^[18]
Eu₂Zr₂O₇	1.60(1 100 ℃)^[17]	—
Gd₂Zr₂O₇	1.91(1 200 ℃)^[18]	11.6(1 200 ℃)^[18]
Dy₂Zr₂O₇	1.34(800 ℃)^[19]	11.1(1 200 ℃)^[20]
Er₂Zr₂O₇	1.49(800 ℃)^[19]	—
Yb₂Zr₂O₇	1.58(800 ℃)^[19]	—

稀土锆酸盐热障涂层材料的研究进展

Research progress of rare-earth zirconate thermal barrier coatings

RichHTML

PDF

可视化

摘要/Abstract

引用本文

使用本文

图/表 3

参考文献 45

相关文章 8

编辑推荐

Metrics

本文评价

[1]	刘保侠, 张盟, 周绪强, 牛云松, 黄迪, 杨沁乾, 鲍泽斌, 朱圣龙. 高能等离子喷涂垂直裂纹氧化锆热障涂层工艺及结合性能研究[J]. 耐火材料, 2024, 58(4): 284-289.
[2]	王瑞达, 赵世贤, 陈留刚, 司瑶晨, 李凌锋, 李红霞, 刘广华. (Y_0.2Gd_0.2Dy_0.2La_0.2Sm_0.2)TaO₄高熵陶瓷材料的结构、性能及抗侵蚀行为研究[J]. 耐火材料, 2023, 57(5): 417-422.
[3]	麦海香, 赵飞, 安建成, 王亚利, 连伟康胡杨, 葛铁柱, 刘新红. 热处理温度对矾土基莫来石材料结构及晶体生长的影响[J]. 耐火材料, 2023, 57(4): 314-319.
[4]	刘涛, 马北越, 昝文宇. 稀土盐类热障/环境障涂层研究现状[J]. 耐火材料, 2023, 57(2): 175-179.
[5]	刘坤 ,高帅波, 仇知, 郭静霓, 邢鹏飞, 闫姝, 冯忠宝, 都兴红. 利用晶体硅砂浆切割废料原位合成高品质SiC/B4C复合陶瓷粉[J]. , 2020, 54(1): 5-9.
[6]	梁志瑜，颜桂炀，郑柳萍，许美真. 利用废催化裂化平衡剂和工业Al2O3合成莫来石[J]. , 2014, 48(3): 211-213.
[7]	刘树信王海滨. 稀土Gd添加氧化锆的物相分析[J]. , 2011, 45(5): 341-0.
[8]	云斯宁. 蒋明学. 李勇. 刘建龙. . AlON陶瓷材料的结构、性质及应用 [J]. , 2003, 37(3): 173-176.