轻量化耐火材料的研制与应用

doi:10.3969/j.issn.1001-1935.2021.04.008

耐火材料 ›› 2021, Vol. 55 ›› Issue (4): 309-315.DOI: 10.3969/j.issn.1001-1935.2021.04.008

轻量化耐火材料的研制与应用

顾华志(), 付绿平, 黄奥, 张美杰, 邹阳

武汉科技大学省部共建耐火材料与冶金国家重点实验室湖北武汉 430081

收稿日期:2021-02-02 出版日期:2021-08-15 发布日期:2021-08-22
作者简介:顾华志:男,1964年生,教授。E-mail: guhuazhi@wust.edu.cn

Design,fabrication and application of lightweight refractories

Gu Huazhi(), Fu Lyuping, Huang Ao, Zhang Meijie, Zou Yang

The State Key Laboratory of Refractories and Metallurgy,Wuhan University of Science and Technology,Wuhan 430081,Hubei,China

Received:2021-02-02 Online:2021-08-15 Published:2021-08-22

摘要/Abstract

摘要：

基于“骨料微孔化、基质紧密化”的研究思路,采用显气孔率低、闭口气孔率高、热导率比普通耐火材料低20%~50%、抗渣性能与普通原料相当的具有微纳米尺度晶内气孔的微孔刚玉和矾土以及镁砂为原料,根据颗粒紧密堆积理论,对Dinger-Funk方程进行修正,建立轻量耐火材料基质堆积密度预测模型,制备了轻量铝镁浇注料。结果表明:此轻量铝镁浇注料不仅抗热震性好,热导率小,而且抗渣性能与普通铝镁浇注料相当。实际应用表明,采用微孔刚玉为骨料制备的钢包工作层用Al₂O₃-MgO质预制块使用寿命在同等条件下均优于现行材料。

关键词: 轻量化, 微孔骨料, 基质紧密化, 铝镁浇注料

Abstract:

Based on the proposal of “micro-pored aggregates and dense-packed matrixes” and the particle dense packing theory,the Dinger-Funk Equation was modified to establish a prediction model of matrix packing density for lightweight refractories.Lightweight alumina magnesia castables were prepared using micro-pore corundum,bauxite and magnesia as starting materials.The micro-pore corundum used has low apparent density,high closed porosity,low thermal conductivity (20%-50% lower than the common corundum),similar slag resistance of the common corundum and micro- or nano-sized intracrystalline pores.The results show that the lightweight alumina magnesia castables not only have good thermal shock resistance and low thermal conductivity,but also have the same slag resistance as the common alumina magnesia castables.The onsite application shows that the service life of the alumina magnesia precast blocks for the ladle working lining prepared with the microporous corundum as aggregates are better than that of the current materials with the same conditions.

Key words: lightweight, microporous aggregates, dense-packed matrix, alumina-magnesia castables

中图分类号:

TQ175

顾华志, 付绿平, 黄奥, 张美杰, 邹阳. 轻量化耐火材料的研制与应用[J]. 耐火材料, 2021, 55(4): 309-315.

Gu Huazhi, Fu Lyuping, Huang Ao, Zhang Meijie, Zou Yang. Design,fabrication and application of lightweight refractories[J]. Refractories, 2021, 55(4): 309-315.

图/表 14

参考文献 9

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项目	普通刚玉	微孔刚玉A	微孔刚玉B
体积密度/(g·cm^-3)	3.63	3.22	3.56
显气孔率/%	3	9	1
闭口气孔率/%	5	10	9
热导率/(W·m^-1·K^-1) (800 ℃)	7.90	3.73	4.86

项目	普通刚玉	微孔刚玉A	微孔刚玉B
体积密度/(g·cm^-3)	3.63	3.22	3.56
显气孔率/%	3	9	1
闭口气孔率/%	5	10	9
热导率/(W·m^-1·K^-1) (800 ℃)	7.90	3.73	4.86

项目	普通矾土	微孔矾土	普通镁砂	微孔镁砂
体积密度/(g·cm^-3)	3.41	3.22	3.18	3.23
显气孔率/%	4	1	5	1
闭口气孔率/%	1	10	6	8
热导率/(W·m^-1·K^-1) (800 ℃)	5.14	3.89	4.37	3.29

项目	普通矾土	微孔矾土	普通镁砂	微孔镁砂
体积密度/(g·cm^-3)	3.41	3.22	3.18	3.23
显气孔率/%	4	1	5	1
闭口气孔率/%	1	10	6	8
热导率/(W·m^-1·K^-1) (800 ℃)	5.14	3.89	4.37	3.29

项目	处理条件	普通铝镁浇注料	轻量铝镁浇注料A	轻量铝镁浇注料B
体积密度/ (g·cm^-3 )	110 ℃, 24 h	3.08	2.81	3.12
显气孔率/ %		14.0	14.2	13.2
常温抗折强度/MPa		10.97	11.59	7.6
常温耐压强度/MPa		55	80	47
线变化率/%	1 000 ℃, 3 h	+0.06	+0.01	+0.05
体积密度/(g·cm^-3)		3.09	2.82	3.08
显气孔率/%		18.8	18.7	16.1
常温抗折强度/MPa		8.92	9.30	5.3
常温耐压强度/MPa		54	61	42
线变化率/%	1 600 ℃, 3 h	+2.52	+0.47	+0.73
体积密度/(g·cm^-3)		3.05	2.78	3.03
显气孔率/%		19.1	18.7	19.0
常温抗折强度/MPa		15.8	13.5	14.1
常温耐压强度/MPa		56	106	72
抗热震性/次(烧后标砖, 1 100 ℃水冷)		9	16	13
800 ℃下热导率/ (W·m^-1·K^-1)		0.929	0.794	0.786

轻量化耐火材料的研制与应用

Design,fabrication and application of lightweight refractories

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类别	侵蚀指数/%	渗透指数/%
普通铝镁浇注料	32.9	86.9
轻量铝镁浇注料A	19.4	64.5
轻量铝镁浇注料B	13.6	80.7

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