耐火材料 ›› 2025, Vol. 59 ›› Issue (6): 471-476.DOI: 10.3969/j.issn.1001-1935.2025.06.003

• 资源综合利用 • 上一篇    下一篇

铝碳复合滑板再生料加入量对Al2O3-SiC-C浇注料性能的影响

陈聪1), 韩兵强1), 魏佳炜2), 钟虎堂1), 赵浩浩1), 段俊龙3)   

  1. 1)武汉科技大学 先进耐火材料全国重点实验室 湖北武汉 430081
    2)洛阳理工学院 材料科学与工程学院 河南洛阳 471023
    3)上海利尔耐火材料有限公司 上海 200949
  • 收稿日期:2025-01-23 出版日期:2025-12-15 发布日期:2025-12-23
  • 通讯作者: 韩兵强,男,1973年生,博士,教授。E-mail:hbqref@wust.edu.cn
  • 作者简介:陈聪:男,2000年生,硕士研究生。E-mail:2959521315@qq.com
  • 基金资助:
    湖北省科技计划项目(2024CSA075)。

Effects of recycled Al2O3-C composite slide gate material addition on properties of Al2O3-SiC-C castables

Chen Cong, Han Bingqiang, Wei Jiawei, Zhong Hutang, Zhao Haohao, Duan Junlong   

  1. First author’s address:State Key Laboratory of Advanced Refractories,Wuhan University of Science and Technology,Wuhan 430081,Hubei,China
  • Received:2025-01-23 Online:2025-12-15 Published:2025-12-23

摘要: 现有滑板服役周期短,导致了高质量原材料的大量浪费,将用后滑板回收到合适的耐火材料中可以降低成本并获得相近的性能。以高铝矾土、铝碳复合滑板再生料(简称“再生料”)、SiC为骨料,以白刚玉粉、SiO2微粉、Si粉、α-Al2O3微粉、Secar 71水泥、球状沥青为细粉,制备了Al2O3-SiC-C(ASC)浇注料。研究了再生料的性能特点,以及再生料等量代替高铝矾土的替代量(替代质量分数分别为0、6%、12%、18%、24%)对ASC浇注料性能的影响。结果表明:1)再生料的Al2O3含量与矾土的接近,并同时含有石墨、Al、Si,再生料的体积密度低于高铝矾土的;2)再生料的引入促进了ASC浇注料中SiC晶须的生成,提高了ASC浇注料的常温强度和抗热震性能;3)再生料具有更高的反应活性,能够通过反应烧结增强与基质间的结合,阻碍熔渣进一步渗透,提高ASC浇注料的抗渣侵蚀性能,添加24%(w)再生料的ASC浇注料可以满足出铁沟的性能要求。

关键词: 再生料, Al2O3-SiC-C浇注料, 抗热震性, 抗渣侵蚀性

Abstract: The short service life of the currently used slide gates leads to significant waste of high-quality raw materials.Recycling spent slide gate materials into appropriate refractories can reduce costs and achieve comparable performance.In this work,Al2O3-SiC-C (ASC) castables were prepared using bauxite,the recycled alumina-carbon composite slide gate materials (abbreviated as “recycled material” hereinafter) and SiC as aggregates,and white corundum powder,SiO2 micropowder,Si powder,α-Al2O3 micropowder,Secar 71 cement and spherical asphalt as fine powders.The performance of the recycled materials and the influence of the recycled materials addition to substitute for the bauxite (0,6%,12%,18%,and 24%,by mass) on the properties of the ASC castables were investigated.The results show that:(1)the recycled material has similar Al2O3 content to bauxite,containing graphite,Al,and Si,and slightly lower bulk density;(2)the introduction of the recycled material promotes the generation of SiC whiskers in the ASC castables,improving the cold strength and thermal shock resistance;(3)the recycled material exhibits higher reactivity,which can enhance the bonding with the matrix through reactive sintering,hinder further slag penetration and improve the slag corrosion resistance of the ASC castables;the ASC castables with 24% recycled material meet the performance requirements for the iron trough.

Key words: recycled material, Al2O3-SiC-C castables, thermal shock resistance, slag corrosion resistance

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