Research progress on hot performance of reaction sintered silicon carbide

doi:10.3969/j.issn.1001-1935.2022.01.017

Abstract

Abstract:

Reaction sintered silicon carbide is a high-density,low-cost and net-shape forming material with excellent mechanical properties,corrosion resistance and oxidation resistance.However,free silicon often remains due to the special process of the reaction sintering method,seriously damaging its hot properties.The research status of the hot mechanical properties,the oxidation resistance,the thermal conductivity and the thermal shock resistance of the reaction sintered silicon carbide was expounded.The main measures to reduce the free silicon and to improve the mechanical properties in recent years were summarized,including the optimization of the preparation process as well as the introduction of the reinforcement and toughening phases.The future research direction of the reaction sintered silicon carbide was prospected.

Key words: reaction sintering, silicon carbide, free silicon, hot properties, preparation process, carbon density, reinforcement and toughening phase

摘要：

反应烧结碳化硅具有优良的力学性能、抗侵蚀性能和抗氧化性能等优点,是一种高致密度、低成本和净尺寸成型的材料。但由于反应烧结法的特殊工艺,反应烧结碳化硅中常含有较多游离硅,严重损害了材料的高温性能。主要阐述了反应烧结碳化硅高温力学性能、抗氧化性能、导热性能和抗热震性能的研究现状,并总结了近年来降低游离硅含量、提高反应烧结碳化硅力学性能的主要措施,包括优化材料制备工艺、引入补强增韧相。并展望了反应烧结碳化硅未来的研究方向。

关键词: 反应烧结, 碳化硅, 游离硅, 高温性能, 制备工艺, 碳密度, 补强增韧相

CLC Number:

TQ174.75

Dong Bo, Yu Chao, Deng Chengji, Zhu Hongxi, Ding Jun, Zhu Qingyou. Research progress on hot performance of reaction sintered silicon carbide[J]. Refractories, 2022, 56(1): 75-81.

董博, 余超, 邓承继, 祝洪喜, 丁军, 朱青友. 反应烧结碳化硅高温性能的研究进展[J]. 耐火材料, 2022, 56(1): 75-81.

References 55

[1]	昝文宇, 马北越. 高纯SiC微粉制备进展[J]. 耐火材料, 2021,55(2):161-168.
[2]	李辰冉, 谢志鹏, 康国兴, 等. 国内外碳化硅陶瓷材料研究与应用进展[J]. 硅酸盐通报, 2020,39(5):1353-1370.
[3]	郝寅雷, 赵文兴, 翁志成. 新型反射镜材料——碳化硅[J].宇航材料工艺, 2001,31(4):11-14+53.
[4]	盛况, 郭清, 张军明, 等. 碳化硅电力电子器件在电力系统的应用展望[J].中国电机工程学报, 2012, 32(30):1-7+3.
[5]	张勇, 何新波, 曲选辉, 等. 碳化硅陶瓷的放电等离子烧结[J]. 北京科技大学学报, 2008,30(12):1414-1417.
[6]	ŠAJGALÍK P, SEDLÁCEK J, LENCÉŠ Z, et al. Additive-free hot-pressed silicon carbide ceramics—A material with exceptional mechanical properties[J]. Journal of the European Ceramic Society, 2016,36(6):1333-1341.
[7]	佘继红, 江东亮, 谭寿洪, 等. 碳化硅陶瓷的热等静压烧结[J]. 硅酸盐学报, 1997,25(4):395-400.
[8]	LI Y S, YIN J, WU H B, et al. High thermal conductivity in pressureless densified SiC ceramics with ultra-low contents of additives derived from novel boron-carbon sources[J]. Journal of the European Ceramic Society, 2014,34(10):2591-2595.
[9]	王艳香, 谭寿洪, 江东亮. 反应烧结碳化硅的研究与进展[J]. 无机材料学报, 2004,19(3):456-462.
[10]	艾俊迪, 余超, 董博, 等. 添加Al粉对反应烧结碳化硅性能和结构的影响[J]. 耐火材料, 2021,55(1):51-55.
[11]	SONG N, ZHANG H B, LIU H,et al. Effects of SiC whiskers on the mechanical properties and microstructure of SiC ceramics by reactive sintering[J]. Ceramics International, 2017,43(9):6786-6790.
[12]	HAYUN S, FRAGE N, DARIEL M P. The morphology of ceramic phases in BxC-SiC-Si infiltrated composites[J]. Journal of Solid State Chemistry, 2006,179(9):2875-2879.
[13]	LI S, ZHANG Y M, HAN J C,et al. Random chopped fibers in reaction bonded SiC composite:Morphology,etching and reinforcing properties[J]. Materials Science and Engineering A, 2012,551:104-109.
[14]	CHAKRABARTI O P, DAS P K. High temperature load-deflection behaviour of reaction bonded SiC (RBSC)[J]. Ceramics International, 2001,27(5):559-563.
[15]	LIU W, CHENG L F, WANG Y G,et al. Investigation of the residual stress in reaction-bonded SiC under irradiation[J]. Journal of the European Ceramic Society, 2016,36(16):3901-3907.
[16]	HUANG Q W, ZHU L H. High-temperature strength and toughness behaviors for reaction-bonded SiC ceramics below 1 400 ℃[J]. Materials Letters, 2005,59(14-15):1732-1735.
[17]	RAO X S, ZHANG F H, LUO X C,et al. Characterization of hardness,elastic modulus and fracture toughness of RB-SiC ceramics at elevated temperature by Vickers test[J]. Materials Science and Engineering A, 2019,744:426-435.
[18]	HUANG Q W, JIN Z H. The high temperature oxidation behavior of reaction-bonded silicon carbide[J]. Journal of Materials Processing Technology, 2001,110(2):142-145.
[19]	KIM H W, KIM H E, SONG H,et al. Effect of oxidation on the room-temperature flexural strength of reaction-bonded silicon carbides[J]. Journal of the American Ceramic Society, 1999,82(6):1601-1604.
[20]	SHAN Q L, HU J B, YANG J S,et al. Oxidation behavior of Al₂O₃ added reaction-sintered SiC ceramics in wet oxygen environment at 1 300 ℃[J]. Journal of Asian Ceramic Societies, 2018,6(3):254-261.
[21]	LIM C B, YANO T, ISEKI T. Microstructure and mechanical properties of RB-SiC/MoSi₂ composite[J]. Journal of Materials Science, 1989,24(11):4144-4151.
[22]	SLACK G A. Thermal conductivity of pure and impure silicon,silicon carbide,and diamond[J]. Journal of Applied Physics, 1965,35(12):3460-3466.
[23]	NAKANO H, WATARI K, KINEMUCHI Y,et al. Microstructural characterization of high-thermal-conductivity SiC ceramics[J]. Journal of the European Ceramic Society, 2004,24(14):3685-3690.
[24]	李其松. 高热导率SiC陶瓷材料制备及应用研究[D]. 济南:山东大学, 2016.
[25]	ZHANG Y Y, HSU C Y, AUBUCHON S,et al. Microstructural and thermal property evolution of reaction bonded silicon carbide (RBSC)[J]. Journal of Alloys and Compounds, 2018,764:107-111.
[26]	雷海波. 再结晶碳化硅陶瓷抗氧化及抗热震性能研究[D]. 长沙:湖南大学, 2010.
[27]	HASSELMAN D P H. Grifjfith criterion and thermal shock resistance of single-phase versus multiphase brittle ceramics[J].Journal of the American Ceramic Society,l969, 52(5):288-289.
[28]	朱丽慧, 黄清伟. 反应烧结碳化硅材料的抗热震性能研究[J]. 耐火材料, 2001,35(4):202-204.
[29]	李连跃, 孙洪鸣, 田素贵, 等. 炭黑含量对反应烧结碳化硅组织与性能的影响[J]. 中国陶瓷工业, 2017,24(1):18-22.
[30]	SONG S C, LU B H, GAO Z Q,et al. Microstructural development and factors affecting the performance of a reaction-bonded silicon carbide composite[J]. Ceramics International, 2019,45(14):17987-17995.
[31]	SUYAMA S, KAMEDA T, ITOH Y. Development of high-strength reaction-sintered silicon carbide[J]. Diamond and Related Materials, 2003,12(3-7):1201-1204.
[32]	杨新领, 郑奔, 李志强, 等. 碳化硅粒度对反应烧结碳化硅陶瓷显微结构与性能的影响[J]. 科技创新导报, 2016,13(2):29-31.
[33]	刘开松. 凝胶注模成型制备反应烧结碳化硅性能的研究[D]. 武汉:武汉理工大学, 2011.
[34]	邓明进, 武七德, 吉晓莉, 等. 酚醛树脂对反应烧结碳化硅显微结构与性能的影响[J]. 耐火材料, 2008,42(4):267-270.
[35]	付旻慧, 刘凯, 刘洁, 等. 碳化硅零件的激光选区烧结及反应烧结工艺[J]. 中国机械工程, 2018,29(17):2111-2118.
[36]	MEYERS S, LEERSNIJDER L D, VLEUGELS J,et al. Direct laser sintering of reaction bonded silicon carbide with low residual silicon content[J]. Journal of the European Ceramic Society, 2018,38(11):3709-3717.
[37]	杨新领, 章潇, 贾马龙, 等. 成型压力对反应烧结碳化硅显微结构与性能的影响[J].材料导报, 2015, 29(S2):536-537+567.
[38]	崔聪聪, 张舸. 前驱体浸渍对反应烧结碳化硅性能的影响[C]// 2015光学精密工程论坛论文集,长春, 2015: 184-189.
[39]	GRINCHUK P S, KIYASHKO M V, ABUHIMD H M,et al. Effect of technological parameters on densification of reaction bonded Si/SiC ceramics[J]. Journal of the European Ceramic Society, 2018,38(15):4815-4823.
[40]	巫红燕, 张国军, 王伟春. 烧结温度对反应烧结碳化硅组织与性能的影响[J]. 粉末冶金技术, 2017,35(5):342-346.
[41]	ZHANG N L, YANG J F, DENG Y C,et al. Preparation and properties of reaction bonded silicon carbide (RB-SiC) ceramics with high SiC percentage by two-step sintering using compound carbon sources[J]. Ceramics International, 2019,45(12):15715-15719.
[42]	黄清伟, 高积强, 金志浩. 热处理温度对反应烧结碳化硅材料组织与性能的影响[J]. 耐火材料, 2000,34(1):17-19.
[43]	BERJONNEAU J, CHOLLON G, LANGLAIS F. Deposition process of Si-B-C ceramics from CH₃SiC_l3/BC_l3/H₂ precursor[J]. Thin Solid Films, 2008,516(10):2848-2857.
[44]	AROATI S, CAFRI M, DILMAN H,et al. Preparation of reaction bonded silicon carbide (RBSC) using boron carbide as an alternative source of carbon[J]. Journal of the European Ceramic Society, 2011,31(5):841-845.
[45]	HAN I S, LEE K S, SEO D W,et al. Improvement of mechanical properties in RBSC by boron carbide addition[J]. Journal of Materials Science Letters, 2002,21(9):703-706.
[46]	MUÑOZ A, FERNÁNDEZ J M, RODRÍGUEZ A D, et al. High-temperature compressive strength of reaction-formed silicon carbide (RFSC) ceramics[J]. Journal of the European Ceramic Society, 1998,18(1):65-68.
[47]	JUNG Y I, PARK D J, PARK J H,et al. Effect of TiSi₂/Ti₃SiC₂ matrix phases in a reaction-bonded SiC on mechanical and high-temperature oxidation properties[J]. Journal of the European Ceramic Society, 2016,36(6):1343-1348.
[48]	李可琢, 张海军, 苑高千, 等. 聚碳硅烷制备SiC陶瓷研究进展[J]. 耐火材料, 2020,54(3):260-265.
[49]	王军凯, 邓先功, 张海军, 等. 碳纳米管增强碳复合耐火材料的研究进展[J].耐火材料, 2016, 50(2):150-154+157.
[50]	曾凡, 陈建军, 姜敏, 等. SiC纳米线增强反应烧结碳化硅陶瓷的性能研究[J]. 硅酸盐通报, 2018,37(2):586-590.
[51]	XUE R, LIU P, ZHANG Z J,et al. Improvement of toughness of reaction bonded silicon carbide composites reinforced by surface-modified SiC whiskers[J]. Ceramics International, 2021,47(13):18150-18156.
[52]	SONG N, LIU H, FANG J Z. Fabrication and mechanical properties of multi-walled carbon nanotube reinforced reaction bonded silicon carbide composites[J]. Ceramics International, 2016,42(1):351-356.
[53]	宋索成, 鲍崇高, 陈子晗, 等. 碳纤维改性反应烧结碳化硅陶瓷组织及力学性能[J]. 西安交通大学学报, 2017, 51(4):67-71+108.
[54]	ZHANG Y M, LI S, HAN J C,et al. Fabrication and characterization of random chopped fiber reinforced reaction bonded silicon carbide composite[J]. Ceramics International, 2012,38(2):1261-1266.
[55]	LI S, ZHANG Y M, HAN J C,et al. Effect of carbon particle and carbon fiber on the microstructure and mechanical properties of short fiber reinforced reaction bonded silicon carbide composite[J]. Journal of the European Ceramic Society, 2013,33(4):887-896.