h-BN在耐火材料和冶金用高温陶瓷中的应用进展

doi:10.3969/j.issn.1001-1935.2023.04.018

耐火材料 ›› 2023, Vol. 57 ›› Issue (4): 360-364.DOI: 10.3969/j.issn.1001-1935.2023.04.018

h-BN在耐火材料和冶金用高温陶瓷中的应用进展

贺远航¹⁾, 钱凡¹⁾, 郭海荣²⁾, 李化龙²⁾, 路跃¹⁾, 刘国齐¹⁾, 李红霞¹⁾

1)中钢集团洛阳耐火材料研究院有限公司先进耐火材料国家重点实验室河南洛阳 471039
2)江苏省沙钢钢铁研究院有限公司江苏苏州 215625

收稿日期:2022-08-24 出版日期:2023-08-15 发布日期:2023-08-30
通讯作者: 刘国齐,男,1975年生,正高级工程师。E-mail:liugq@lirrc.com
作者简介:贺远航:男,1997年生,硕士研究生。E-mail:3537982669@qq.com
基金资助:
国家重点研发计划项目(2021YFB3701400)。

Application progress of h-BN in refractories and high temperature ceramics for metallurgy

He Yuanhang, Qian Fan, Guo Hairong, Li Hualong, Lu Yue, Liu Guoqi, Li Hongxia

First author’s address:State Key Laboratory of Advanced Refractories,Sinosteel Luoyang Institute of Refractories Research Co.,Ltd.,Luoyang 471039,Henan,China

Received:2022-08-24 Online:2023-08-15 Published:2023-08-30

摘要/Abstract

摘要： h-BN具有优异的抗热震性和化学稳定性,具有类石墨层状结构,在冶金、化工、电子等领域应用广泛。综述了h-BN在耐火材料中的研究应用情况,包括h-BN对耐火材料抗热震性、抗氧化性和抗渣性的改善,以及对耐火材料烧结性的影响;概述了热压烧结h-BN复合材料在钢铁冶金关键部件的应用及其力学性能、抗热震性、抗氧化性和抗钢液侵蚀性的改善措施;指出了h-BN在耐火材料及冶金用高温陶瓷应用中存在的问题。

关键词: h-BN, 石墨, 抗热震性, 抗氧化性, 抗渣性, 抗钢液侵蚀性

Abstract: h-BN has excellent thermal shock resistance and chemical stability.It has a graphite-like layered structure and is widely used in metallurgy,chemical industry,electronics and other fields.The research and application of h-BN in refractories were reviewed,including the improvement of the thermal shock resistance,oxidation resistance,and slag resistance of refractories by h-BN,as well as its effect on the sintering properties of refractories.The application of hot-pressed sintered h-BN composites in key components of iron and steel metallurgy and the improvement measures of the mechanical properties,thermal shock resistance,oxidation resistance and corrosion resistance to molten steel were summarized.The problems existing in the application of h-BN in refractories and high temperature ceramics for metallurgy were pointed out.

Key words: h-BN, graphite, thermal shock resistance, oxidation resistance, slag resistance, corrosion resistance to molten steel

中图分类号:

TQ175

贺远航, 钱凡, 郭海荣, 李化龙, 路跃, 刘国齐, 李红霞. h-BN在耐火材料和冶金用高温陶瓷中的应用进展[J]. 耐火材料, 2023, 57(4): 360-364.

He Yuanhang, Qian Fan, Guo Hairong, Li Hualong, Lu Yue, Liu Guoqi, Li Hongxia. Application progress of h-BN in refractories and high temperature ceramics for metallurgy[J]. Refractories, 2023, 57(4): 360-364.

参考文献

[1] PEREVISLOV S N.Structure,properties,and applications of graphite-like hexagonal boron nitride[J].Refractories and Industrial Ceramics,2019,60(3):291-295.
[2] 景捷.六方氮化硼陶瓷的制备与性能研究[D].济南:山东大学,2018.
[3] JI Z X,LIAO N,LI Y W, et al.Effect of h-BN on the microstructure and fracture behavior of low carbon Al₂O₃-C refractories[J].Ceramics International,2021,47(21):29900-29907.
[4] LIANG F,XUE Z L,ZHAO L,et al.Mechanical properties and thermal shock resistance of alumina/hexagonal boron nitride composite refractories[J].Metallurgical and Materials Transactions A,2015,46(9):4335-4341.
[5] 丁成栋,秦庆伟,杨建红,等.h-BN加入量对低水泥刚玉质浇注料性能的影响[J].耐火材料,2012,46(3):203-205.
[6] 遇龙,罗旭东,张国栋,等.BN对镁基含碳耐火材料性能的影响[J].人工晶体学报,2015,44(1):227-232+242.
[7] 黄健,韩兵强,鄢文,等.BN粉加入量对Al₂O₃-SiC-C浇注料性能的影响[J].耐火材料,2019,53(5):354-358.
[8] 杨松,涂军波,李德民,等.氮化硼加入量对铁沟浇注料性能的影响[J].工业炉,2020,42(2):17-20.
[9] 牛世程,吴吉光,梁鹏鹏,等.BN微粉加入量对Si₃N₄/BN复合材料的高温抗氧化性的影响[J].耐火材料,2022,56(6):495-498+504
[10] 赵顺,李亚伟,李友胜,等.BN对Al₂O₃-MgO系浇注料性能的影响[J].耐火材料,2004,38(6):402-406.
[11] 赵海雷,李文超,钟香崇,等.氮化硼对锆刚玉莫来石材料力学性能及显微结构的影响[J].硅酸盐学报,1994(5):509-515.
[12] BARICK P,SAHA B P.Effect of boron nitride addition on densification,microstructure,mechanical,thermal,and dielectric properties of β-SiAlON ceramic[J].Journal of Materials Engineering and Performance,2021,30(5):3603-3611.
[13] LI Y J,LIU D H,CAI Y Z,et al.Improved thermal shock resistance of β-SiAlON/h-BN composite prepared by a precursor infiltration pyrolysis (PIP) route[J].Ceramics International,2020,46 (10):16932-16937.
[14] 陈磊,王玉金,周玉,等.薄带连铸用侧封板材料的研究进展[J].耐火材料,2014,48(2):155-160.
[15] 李晓雨,王静,庞靖,等.铁基非晶带材的制备技术现状及应用展望[C]//第十届中国钢铁年会暨第六届宝钢学术年会论文集,上海,2015:830-835.
[16] 廖宁,李亚伟,桑绍柏.一种用于制备非晶薄带的氮化硼基喷嘴耐火材料及其制备方法:CN110066184A [P].2019-07-30.
[17] 甄强,李文超.水平连铸用分离环的研究现状[J].耐火材料,1998(4):234-237.
[18] 田汉蒲,徐景峰,崔泽南,等.水平连铸分离环碎裂的分析和改进措施[J].特殊钢,2005 (4):46-48.
[19] 段小明,杨治华,王玉金,等.六方氮化硼(h-BN)基复合陶瓷研究与应用的最新进展[J].中国材料进展,2015,34 (10):770-782.
[20] CHEN L,HUANG Y H,WANG Y J,et al.Effect of ZrO₂ content on microstructure,mechanical properties and thermal shock resistance of (ZrB₂+3Y-ZrO₂)/BN composites[J].Materials Science and Engineering A,2013,573:106-110.
[21] ZHAI F R,LI S,SUN J L,et al.Microstructure,mechanical properties and thermal shock behavior of h-BN-SiC ceramic composites prepared by spark plasma sintering[J].Ceramics International,2017,43(2):2413-2417.
[22] 翟凤瑞.六方氮化硼陶瓷的放电等离子烧结及性能研究[D].北京:北京科技大学,2017.
[23] CHEN L,WANG Y J,RAO J C,et al.Influence of ZrO₂ content on the performances of BN-ZrO₂-SiC composites for application in the steel industry[J].International Journal of Applied Ceramic Technology,2015,12(1):184-191.
[24] 赵海雷,李文超,钟香崇,等.锆刚玉莫来石-氮化硼系复合材料抗热震性的研究[J].硅酸盐学报,1996 (3):311-316.
[25] LIAO N,NIU B,QIU B F,et al.Enhanced thermal shock resistance of BN-based composites sintered by hot-pressing with the introduction of nano oxides[J].Materials Science and Engineering A,2019,767:138443.
[26] 李永利,张久兴,乔冠军,等.氧化物/BN可加工复相陶瓷的高温氧化行为及表面裂纹修复[J].硅酸盐学报,2004 (12):1476-1480.
[27] YANG Z H,JIA D C,ZHOU Y,et al.Oxidation resistance of hot-pressed SiC-BN composites[J].Ceramics International,2006,34(2):317-321.
[28] XU Y,MA T Y,WANG X H,et al.High temperature oxidation resistance of hot-pressed h-BN/ZrO₂ composites[J].Ceramics International,2014,40(7):11171-11176.
[29] QIAN F,GUO H R,HE Y H,et al.Corrosion mechanism of BN-ZrO₂ based side-dam by molten steel[J].Journal of the European Ceramic Society,2022,42 (9):3996-4005.
[30] CHEN L,ZHEN L,WANG Y J,et al.Corrosion behavior and microstructural evolution of BN-ZrO₂-SiC composites in molten steel[J].International Journal of Applied Ceramic Technology,2017,14(4):665-674.
[31] LIAO N,QIU B F,NATH M,et al.Effects of nano ZrO₂ content on the comprehensive properties of BN-SiC composites[J].Journal of Alloys and Compounds,2020,813:152180.
[32] CHEN L,WANG Y J,YAO M Y,et al.Corrosion kinetics and corrosion mechanisms of BN-ZrO₂-SiC composites in molten steel[J].Corrosion Science,2014,89:93-100.
[33] QIAN F,LI H L,YANG W G,et al.Corrosion resistance of BN-ZrO₂ ceramics with different additives by molten steel[J].Journal of Iron and Steel Research International,2022,29:1101-1109.

h-BN在耐火材料和冶金用高温陶瓷中的应用进展

Application progress of h-BN in refractories and high temperature ceramics for metallurgy

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	李莹, 汪涤, 赵莉, 尹艺程, 贾全利. 石墨类型对Al₂O₃-MgO浇注料性能的影响[J]. 耐火材料, 2024, 58(4): 323-328.
[2]	田朋丹, 王刚, 杜鹏辉, 冯海霞, 王来稳, 潘元帅. 聚丙烯纤维对刚玉-六铝酸钙浇注料抗热震性能的影响[J]. 耐火材料, 2024, 58(3): 208-212.
[3]	梁效诚, 冯雨, 刘中飞, 罗旭东, 黄敏, 吴锋. 预合成CaZrO₃对镁锆质耐火材料性能的影响[J]. 耐火材料, 2024, 58(3): 213-217.
[4]	何维祥, 罗明, 何亮, 柯极峰. 高精炼比模式下钢包渣线镁碳砖的研制及应用[J]. 耐火材料, 2024, 58(3): 234-237.
[5]	孟红涛, 马龙斌, 刘鑫. 预氧化对焦炉用氮化物结合碳化硅材料抗氧化性的影响[J]. 耐火材料, 2024, 58(3): 242-245.
[6]	刘中飞, 冯雨, 梁效诚, 罗旭东, 李广伟, 吴锋. 预合成镁锆砂和煅烧温度对镁锆质材料性能的影响[J]. 耐火材料, 2024, 58(2): 110-115.
[7]	王志强, 徐国涛, 雷中兴, 彭肖仟, 郑吉红, 刘黎, 王心一, 刘毅, 徐炎明. Al₂O₃-MgAl₂O₄复相骨料对刚玉-尖晶石浇注料抗渣性能的影响[J]. 耐火材料, 2024, 58(1): 63-67.
[8]	夏玉婷, 杨文博, 饶羽彤, 聂锐杉, 姚远. 轻质高强莫来石浇注料的组分优化和性能增强[J]. 耐火材料, 2024, 58(1): 72-75.
[9]	刘学新, 张锦化, 陈鑫铭, 王景然, 杨宗源, 韩兵强, 柯昌明. 以微孔刚玉-尖晶石骨料替代刚玉骨料制备刚玉-尖晶石浇注料[J]. 耐火材料, 2023, 57(6): 514-517.
[10]	梁新星, 高玉莹, 叶航, 马成良, 刘小钢, 范崇方, 徐恩霞. 玻璃窑炉用新型氧化锆基复合材料性能研究[J]. 耐火材料, 2023, 57(6): 518-522.
[11]	吕俊毅, 李亚格, 蔡伟杰, 李韬, 许晴, 张海军. 剥离法制备石墨烯的研究进展[J]. 耐火材料, 2023, 57(6): 546-552.
[12]	张涛, 谭清华, 冯志源, 王晗, 刘鹏程. 稳定剂种类对高纯氧化锆空心球制品性能的影响[J]. 耐火材料, 2023, 57(5): 397-401.
[13]	韩艺辉, 曹喜营, 冯海霞, 王晖, 柳军, 潘元帅, 王建斌. 不同结合剂结合MgO-C耐火材料的性能研究[J]. 耐火材料, 2023, 57(5): 402-406.
[14]	章健, 章艺, 宋艳艳, 董殿敏, 王波, 胡飘, 刘克. 激光扫描法在全自动抗热震性试验机的应用[J]. 耐火材料, 2023, 57(5): 434-437.
[15]	刘兴刚, 高昕宇, 刘涛, 李玉庆. SiO₂添加量对Mg-PSZ陶瓷性能的影响[J]. 耐火材料, 2023, 57(4): 291-294.