锂离子电池正极用匣钵耐火材料研究进展

doi:10.3969/j.issn.1001-1935.2025.06.016

耐火材料 ›› 2025, Vol. 59 ›› Issue (6): 542-546.DOI: 10.3969/j.issn.1001-1935.2025.06.016

锂离子电池正极用匣钵耐火材料研究进展

彭金琦, 雷辉聪, 黄潇阳, 黄仲, 张海军

武汉科技大学先进耐火材料全国重点实验室湖北武汉 430081

收稿日期:2025-01-22 出版日期:2025-12-15 发布日期:2025-12-23
通讯作者: 黄仲,男,1990年生,博士,副教授。E-mail:huangzhong@wust.edu.cn
作者简介:彭金琦:男,2002年生,硕士研究生。E-mail:qq1974860952@163.com
基金资助:
国家自然科学基金(52202025,U23A20559);武汉科技大学“十四五”湖北省优势特色学科(群)项目(2023A0307)。

Research progress on saggar refractories for lithium-ion battery cathodes

Peng Jinqi, Lei Huicong, Huang Xiao-yang, Huang Zhong, Zhang Haijun

First author’s address:State Key Laboratory of Advanced Refractories,Wuhan University of Science and Technology,Wuhan 430081,Hubei,China

Received:2025-01-22 Online:2025-12-15 Published:2025-12-23

摘要/Abstract

摘要： 匣钵耐火材料是保障锂离子电池正极材料高温生产过程的重要基础材料。简述了正极材料与匣钵耐火材料的侵蚀机制,综述了锂离子电池正极用匣钵耐火材料(莫来石系、堇青石系及其他)的特性,最后指出该研究领域存在的主要问题,并对锂离子电池正极用匣钵耐火材料的未来发展进行了展望。

关键词: 正极材料, 匣钵耐火材料, 抗侵蚀性能

Abstract: Saggar refractories serve as a fundamental material for the high-temperature production of lithium-ion battery cathode materials.The corrosion mechanism between cathode materials and saggar refractories was analyzed,and the characteristics of saggar refractories for lithium-ion battery cathodes were summarized,including mullite,cordierite,and other systems.Finally,the main challenges in this research field were outlined,and the future development of saggar refractories was proposed.

Key words: cathode materials, saggar refractory, corrosion resistance

中图分类号:

TQ175

彭金琦, 雷辉聪, 黄潇阳, 黄仲, 张海军. 锂离子电池正极用匣钵耐火材料研究进展[J]. 耐火材料, 2025, 59(6): 542-546.

Peng Jinqi, Lei Huicong, Huang Xiao-yang, Huang Zhong, Zhang Haijun. Research progress on saggar refractories for lithium-ion battery cathodes[J]. Refractories, 2025, 59(6): 542-546.

参考文献

[1] LI W D,SONG B H,MANTHIRAM A.High-voltage positive electrode materials for lithium-ion batteries[J].Chemical Society Reviews,2017,46(10):3006-3059.
[2] XIANG J W,WEI Y,ZHONG Y,et al.Building practical high-voltage cathode materials for lithium-ion batteries[J].Advanced Materials,2022,34(52):2200912.
[3] WANG Y Z,WANG E R,ZHANG X,et al.High-voltage “single-crystal” cathode materials for lithium-ion batteries[J].Energy & Fuels,2021,35(3):1918-1932.
[4] DU C Y,ZHAO Z Y,LIU H,et al.The status of representative anode materials for lithium-ion batteries[J].The Chemical Record,2023,23(5):e202300004.
[5] LAN Y Q,LI X K,ZHOU G M,et al.Direct regenerating cathode materials from spent lithium-ion batteries[J].Advanced Science,2024,11(1):2304425.
[6] CHEN L G,MALFLIET A,JONES P T,et al.Degradation mechanisms of alumina-silica runner refractories by carbon steel during ingot casting process[J].Ceramics International,2016,42(8):10209-10214.
[7] XIANG K,LI S J,LI Y B,et al.Interactions of Li₂O volatilized from ternary lithium-ion battery cathode materials with mullite saggar materials during calcination[J].Ceramics International,2022,48(16):23341-23347.
[8] ZHAI P T,CHEN L G,YIN Y M,et al.Interactions between mullite saggar refractories and Li-ion battery cathode materials during calcination[J].Journal of the European Ceramic Society,2018,38(4):2145-2151.
[9] DUAN X K,ZHENG H,CHEN Y Q,et al.Study on the corrosion resistance of cordierite-mullite and SiC refractories to Li-ion ternary cathode materials[J].Ceramics International,2020,46(3):2829-2835.
[10] SUN Z H,YU J,ZHAO H Z,et al.Damage mechanism and design optimization of mullite-cordierite saggar used as the sintering cathode material in Li-ion batteries[J].Journal of the European Ceramic Society,2022,42(13):6255-6263.
[11] DUAN X K,QIAN F,CHEN Y Q,et al.Erosion mechanism of Li-ion batteries cathode materials on Si₃N₄-SiC and SiO₂-SiC refractories[C]//11^th International Conference on High-performance Ceramics:CICC-11,Kunming,2019:012101.
[12] 单峙霖,赵惠忠,江文涛,等.锂离子电池正极材料烧成用匣钵材料性能的研究[J].耐火材料,2020,54(4):305-309.
[13] 万治清.锂电池正极材料承烧用堇青石-莫来石复合匣钵材料的制备及其抗侵蚀性能研究[D].银川:北方民族大学,2022.
[14] QIAN F,WANG L G,MA W K,et al.Preparation of cement-based Al₂O₃-MgO-SiO₂ sagger and its corrosion mechanism by cathode material during calcination[J].Corrosion Science,2022,205:110448.
[15] SUN Z H,LI S P,LI H Q,et al.Corrosion behavior of cobalt oxide and lithium carbonate on mullite-cordierite saggar used for lithium battery cathode material sintering[J].Materials,2023,16(2):653.
[16] 张巍,王京阳.莫来石复合耐火材料的应用进展[J].耐火材料,2024,58(1):80-86+92.
[17] XIANG K,LI S J,LI Y B,et al.Firing properties and corrosion resistance of mullite-Al₂TiO₅ saggar materials[J].International Journal of Applied Ceramic Technology,2023,20(3):1928-1938.
[18] 鄢文,陈俊峰,李楠.轻量化刚玉-莫来石耐火材料抗渣性能研究[J].稀有金属材料与工程,2015,44(S1):442-446.
[19] WANG H L,LI Y B,LI S J,et al.Damage mechanism and corrosion resistance improvement of corundum-mullite kiln furniture during calcining of Li-ion cathode materials[J].Journal of the European Ceramic Society,2023,43(12):5390-5397.
[20] 陈洋,邓承继,丁军,等.堇青石-莫来石质匣钵材料抗热震性和抗侵蚀性研究[J].硅酸盐通报,2019,38(5):1550-1555.
[21] SUN Z H,YU J,ZHAO H Z,et al.Research on saggars of lightweight design used to prepare cathode materials for Li-ion batteries[J].Journal of the European Ceramic Society,2023,43(2):692-699.
[22] CAO D K,LI S J,LI Y B,et al.Thermal shock stability and corrosion resistance to LiNi_xCo_yMn_1-x-yO₂ of mullite-cordierite-CA₆ saggar materials[J].International Journal of Applied Ceramic Technology,2025,22(2):e14944.
[23] DING D F,YE G T,CHEN L G.Superior corrosion resistance KAlSi₂O₆-containing materials for calcining Li-ion battery cathode materials[J].Corrosion Science,2019,157:324-330.
[24] DING D F,GUO L,MU Y D,et al.Use of coal gangue to prepare refractory saggars with superior corrosion resistance and thermomechanical properties for the calcination of Li-ion battery cathode materials[J].ACS Sustainable Chemistry & Engineering,2021,9(1):254-263.
[25] BANJURAIZAH J,MOHAMAD H,AHMAD Z A.Thermal expansion coefficient and dielectric properties of non-stoichiometric cordierite compositions with excess MgO mole ratio synthesized from mainly Kaolin and talc by the glass crystallization method[J].Journal of Alloys and Compounds,2010,494(1/2):256-260.
[26] 王不赖,王峰,白志民,等.低热膨胀系数的堇青石陶瓷研究进展[J].耐火材料,2024,58(6):536-542.
[27] ZHENG C Y,ZHANG H,ZHAO H Z,et al.Structural design and corrosion resistance of hibonite-cordierite saggar composite layer[J].International Journal of Applied Ceramic Technology,2024,21(3):2342-2356.
[28] GAN C Q,ZHANG H,ZHAO H Z,et al. Firing properties and erosion resistance of hibonite-cordierite sagger[J].Ceramics International,2022,48(20):30589-30597.
[29] GAN C Q,ZHANG H,ZHAO H Z,et al.Effect of aggregate particle content on sintering and corrosion resistance of hibonite-cordierite saggar[J].Ceramics International,2023,49(1):907-917.
[30] 陈肇友.相图与耐火材料(Ⅲ)[J].耐火材料,2013,47(3):218-231.
[31] 程水明,丛培源,梁永和,等.锂离子电池正极材料用莫来石溶胶结合匣钵材料的性能研究 [J].耐火材料,57(6):495-499.
[32] 陈瑞文.堇青石-莫来石窑具的研制及性能变化研究[J].陶瓷科学与艺术,2008,42(7):4-6.
[33] 赵英娜,任江,常刚,等.堇青石-莫来石-钛酸铝窑具复合材料性能研究[J].中国陶瓷,2014,50(1):48-51.
[34] 陈宁,李素平,丁颖颖,等.烧成工艺对堇青石-莫来石窑具材料性能的影响[J].中国陶瓷,2017,53(1):86-90.
[35] LIU S H,CHEN P,XU D H,et al.Effects of sintering temperature on phases,microstructures and properties of fused silica ceramics[J].Key Engineering Materials,2017,726:399-403.
[36] ZHANG H,ZHANG H,XIAO Z X,et al.Research on sintering performance and corrosion mechanism of whisker enhanced MgAl₂O₄ saggar[J].Ceramics International,2024,50(22):47017-47023.
[37] LIU M Y,LIU X J,LIN F K,et al.Preparation and corrosion resistance of β-Al₂O₃-MgAl₂O₄ multiphase materials for synthesising Li-ion battery cathode materials[J].Ceramics International,2024,50(21):42739-42747.
[38] 王建波,郑翰,相宇博,等.氮化硅结合碳化硅匣钵在合成锂离子三元正极材料上的应用[J].中国陶瓷,2024,60(12):25-30.

锂离子电池正极用匣钵耐火材料研究进展

Research progress on saggar refractories for lithium-ion battery cathodes

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 14

编辑推荐

Metrics

本文评价

[1]	姚丽君, 王官煜, 尹致远, 王志鹏, 温天朋. 锂离子电池正极材料用CA₆匣钵的改性研究[J]. 耐火材料, 2025, 59(4): 311-316.
[2]	姜悦纳, 叶欣健, 陶天一, 杨梦瑶, 林凡凯, 郑晓洪, 孙振华, 吴小文, 黄朝晖. 废旧锂电有价元素提取热处理炉用SiC-Si₃N₄-C质耐侵蚀材料研究[J]. 耐火材料, 2025, 59(3): 224-228.
[3]	韦锦涛, 罗益欣, 杨博林, 刘正龙, 邓骆鹏余超, 邓承继, 王周福, 丁军. La₂O₃对MgO-Mg₂SiO₄质耐火材料力学性能及抗渣侵蚀性的影响[J]. 耐火材料, 2025, 59(2): 111-117.
[4]	薛军柱, 刘光平, 陈俊峰, 魏国平, 程亚苹, 鄢文, 李楠. 尖晶石加入量对刚玉-尖晶石浇注料显微结构和性能的影响[J]. 耐火材料, 2025, 59(2): 155-161.
[5]	罗益欣, 王杏, 刘正龙, 余超, 邓承继, 丁军. h-BN对低碳Al₂O₃-C耐火材料性能的影响[J]. 耐火材料, 2025, 59(1): 13-18.
[6]	屈超, 李杭, 黄潇阳, 张海军, 张少伟. 水泥回转窑用耐火材料研究进展[J]. 耐火材料, 2025, 59(1): 87-92.
[7]	梁新星, 高玉莹, 叶航, 马成良, 刘小钢, 范崇方, 徐恩霞. 玻璃窑炉用新型氧化锆基复合材料性能研究[J]. 耐火材料, 2023, 57(6): 518-522.
[8]	潘元帅, 王刚, 冯海霞, 柳军, 田朋丹, 韩艺辉, 王建斌. 结合剂种类对刚玉-尖晶石浇注料抗镍基高温合金侵蚀性能的影响[J]. 耐火材料, 2023, 57(3): 220-225.
[9]	曹会彦, 郑翰, 钱凡, 吴吉光, 万龙刚, 马昭阳. SiO₂微粉加入量对β-SiAlON-SiC材料性能的影响[J]. 耐火材料, 2023, 57(2): 121-124.
[10]	郑翰, 马昭阳, 曹会彦, 万龙刚, 相宇博, 钱凡, 吴吉光. 匣钵材料抗氢氧化锂侵蚀性研究[J]. 耐火材料, 2023, 57(2): 125-130.
[11]	单峙霖,赵惠忠,江文涛,赵鹏达. 锂电池正极材料烧成用匣钵材料性能的研究[J]. , 2020, 54(4): 305-309.
[12]	段雪珂 ,王新福, 刘国齐, 王龙光, 陈红伟, 钱凡. 锂电池正极材料合成用堇青石-莫来石质匣钵研究进展[J]. , 2020, 54(2): 172-176.
[13]	甘菲芳,石洪志,夏欣鹏. 硅溶胶结合Al2O3-SiC-C浇注料的抗侵蚀性能[J]. , 2008, 42(3): 190-0.
[14]	张悦明，李庆辉，林育炼 . 铝镁炭钢包衬砖抗侵蚀性的研究 [J]. , 1994, 28(1): 26-29.