含碳耐火浇注料的研究现状

doi:10.3969/j.issn.1001-1935.2021.03.016

耐火材料 ›› 2021, Vol. 55 ›› Issue (3): 251-257.DOI: 10.3969/j.issn.1001-1935.2021.03.016

含碳耐火浇注料的研究现状

杨守磊¹^,³⁾(), 丁冬海²⁾, 肖国庆²⁾()

1)郑州航空工业管理学院材料学院河南郑州 450046
2)西安建筑科技大学材料科学与工程学院陕西西安 710055
3)西安建筑科技大学西部绿色建筑国家重点实验室陕西西安 710055

收稿日期:2020-12-10 出版日期:2021-06-15 发布日期:2021-06-24
通讯作者: 肖国庆,男,1967年生,博士,教授。E-mail: xiaoguoqing@xauat.edu.cn
作者简介:杨守磊:男, 1984年生,博士,讲师。E-mail: yangsl@edu.cn
基金资助:
国家自然科学基金资助项目(51772236);国家自然科学基金资助项目(51572212);河南省科技攻关资助项目(202102210019);西部绿色建筑国家重点实验室开放基金资助项目(LSKF202006)

Research status of carbon-containing refractory castables

Yang Shoulei¹^,³⁾(), Ding Donghai²⁾, Xiao Guoqing²⁾()

1)School of Materials Science and Engineering,Zhengzhou University of Aeronautics,Zhengzhou 450046,Henan,China

Received:2020-12-10 Online:2021-06-15 Published:2021-06-24
Contact: Xiao Guoqing

摘要/Abstract

摘要：

总结了国内外采用表面活性剂、造粒、表面涂层等技术将传统碳材料(主要是鳞片石墨)改性优化后应用于耐火浇注料的研究进展,阐述了其工艺特点及目前存在的问题。还介绍了近年来微/纳米碳材料应用于含碳耐火浇注料的研究现状,分析了阻碍微/纳米碳材料应用于含碳耐火浇注料的原因。

关键词: 含碳耐火浇注料, 鳞片石墨, 润湿性, 分散性, 抗氧化性

Abstract:

The application progress of modified and optimized traditional carbon materials (mainly flake graphite) by surfactant,granulation and surface coating into refractory castables in China and overseas was summarized.The process characteristics and current problems were also introduced.The research state of micro/nano-carbon materials applied in carbon containing refractory castables was reviewed,and the preventing reasons were analyzed.

Key words: carbon-containing refractory castables, flake graphite, wettability, dispersion, antioxidation

中图分类号:

TQ175

杨守磊, 丁冬海, 肖国庆. 含碳耐火浇注料的研究现状[J]. 耐火材料, 2021, 55(3): 251-257.

Yang Shoulei, Ding Donghai, Xiao Guoqing. Research status of carbon-containing refractory castables[J]. Refractories, 2021, 55(3): 251-257.

参考文献 64

[1]	LEE W E, VIEIRA W, ZHANG S, et al. Castable refractory concretes[J]. International Materials Reviews, 2001,46(3):145-167. DOI URL
[2]	YANG D X, LIU Y G, FANG M H, et al. Study on the slag corrosion resistance of unfired Al₂O₃-SiC/β-Sialon/Ti(C,N)-C refractories[J]. Ceramics International, 2014,40(1):1593-1598. DOI URL
[3]	LI X C, LI Y X, CHEN L F, et al. Matrix structure evolution and thermo-mechanical properties of carbon fiber-reinforced Al₂O₃-SiC-C castable composites[J]. Materials Research Bulletin, 2015,61:201-206. DOI URL
[4]	GOGTAS C, LOPEZ H F, SOBOLEV K. Role of cement content on the properties of self-flowing Al₂O₃ refractory castables[J]. Journal of the American Ceramic Society, 2014,34(5):1365-1373.
[5]	KUMAR V, SINGH V, SRIVASTAVA A. Low temperature synjournal of high alumina cements by novel co-melt precursors and their implementation as castables with some micro fine additives[J]. Journal of the American Ceramic Society, 2013,96(7):2124-2131. DOI URL
[6]	任俊, 卢寿兹. 亲水性及疏水性颗粒在水中的分散行为研究[J]. 中国粉体技术, 1999,5(2):6-9.
[7]	PARUCHURI V K, NGUYEN A V, MILLER J D. Zeta-potentials of self-assembled surface micelles of ionic surfactants adsorbed at hydrophobic graphite surfaces[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2004,250(1/3):519-526. DOI URL
[8]	王丽丽, 于锦, 李正元. 分散剂对石墨水悬浮液分散性能的影响[J]. 新型炭材料, 2016,31(1):92-96.
[9]	陈云, 冯其明, 张国范, 等. 微细鳞片石墨分散性[J]. 中南大学学报(自然科学版), 2004,35(6):955-959.
[10]	朱伯铨, 管红梅, 刘文超. 以表面活性剂改善水对鳞片石墨的润湿性研究[J]. 武汉冶金科技大学学报(自然科学版), 1999,22(3):242-244.
[11]	OLIVEIRAT I R, SALOMÃ O R, PANDOLFELLI V C, et al. High-carbon-content refractory castables[J]. American Ceramic Society Bulletin, 2003,82(10):9501-9508.
[12]	KANDEL M, ZHOU N S, RIGAUD M, et al. Use of micro-pellets of graphite in Al₂O₃-SiC-C castables[C]// 9^th Internation symposium on industry ceramics,Italy, 1998.
[13]	ZHOU N S. Elaboration of aluminum oxide-based graphite containing castables[D]. Montreal:Université de Montréal, 2000.
[14]	PALCO S, HE H, PARANSKY E, et al. The challenges of adding natural graphite into castables[J]. Interceram:Int Ceram Rev, 2005: 16-19.
[15]	张艳利. 钢包用含碳浇注料的研制[J]. 耐火材料, 2010,44(2):84.
[16]	KITAHARA A, EMA T, KOBAYASHI K, et al. Graphite granulated product for amorphous refractory:JP03088878[P]. 1991-04-15.
[17]	SHARIF S, GOLESTANI-FARD F, SARPOOLAKY H. Improvement of water/resin wettability of graphite using carbon black nano particles coating via ink media[J]. Journal of Alloys and Compounds, 2009,482(1):361-365. DOI URL
[18]	YOSHIMATSU H, FUJIWARA S, KONISHI R, et al. Wettability by water and oxidation resistance of alumina-coated graphite powder[J]. Journal of the Ceramic Society of Japan, 1995,103(9):929-934. DOI URL
[19]	KAWABATA K, YOSHIMATSU H, FUJII E, et al. Effect of Al₂O₃ raw materials on fluidity of Al₂O₃-coated graphite powder slurry[J]. Journal of the Ceramic Society of Japan, 2001,109(5):470-473. DOI URL
[20]	YILMAZ S, KUTMEN-KALPAKLI Y, YILMAZ E. Synjournal and characterization of boehmitic alumina coated graphite by sol-gel method[J]. Ceramics International, 2009,35(5):2029-2034. DOI URL
[21]	ZHANG S W, LEE W E. Improving the water-wettability and oxidation resistance of graphite using Al₂O₃/SiO₂ sol-gel coatings[J]. Journal of the European Ceramic Society, 2003,23(8):1215-1221. DOI URL
[22]	YU J, UENO S, HIRAGUSHI K. Improvement in flowability,oxidation resistance and water wettability of graphite powders by TiO₂ coating[J]. Journal of the Ceramic Society of Japan, 1996,104(4):481-485. DOI URL
[23]	SUNWOO S, KIM J H, LEE K G, et al. Preparation of ZrO₂ coated graphite powders[J]. Journal of Materials Science, 2000,35(14):3677-3680. DOI URL
[24]	WANG R, HASHIMOTO K, FUJISHIMA A, et al. Light-induced amphiphilic surfaces[J]. Nature:International Weekly Journal of Science, 1997,388(6641):431-432.
[25]	MENG B, PENG J H. Effects of in-situ synthesized mullite whiskers on flexural strength and fracture toughness of corundum-mullite refractory materials[J]. Ceramics International, 2013,39(2):1525-1531. DOI URL
[26]	QIN H B, LI H X, WANG J D, et al. Influence of spinel on the fracture energy of refractory castable[J]. Materials Science Forum, 2013, 745-746:632-635. DOI URL
[27]	SABERI A, GOLESTANI-FARD F, SARPOOLAKY H, et al. Development of MgAl₂O₄ spinel coating on graphite surface to improve its water-wettability and oxidation resistance[J]. Ceramics International, 2009,35(1):457-461. DOI URL
[28]	MUKHOPADHYAY S, DUTTA S, ANSAR S A, et al. Spinel-coated graphite for carbon containing refractory castables[J]. Journal of the American Ceramic Society, 2009,92(8):1895-1900. DOI URL
[29]	MUKHOPADHYAY S. Improved sol-gel spinel (MgAl₂O₄) coatings on graphite for application in carbon containing high alumina castables[J]. Journal of Sol-Gel Science and Technology, 2010,56(1):66-74. DOI URL
[30]	ANSAR S A, BHATTACHARYA S, DUTTA S, et al. Development of mullite and spinel coatings on graphite for improved water-wettability and oxidation resistance[J]. Ceramics International, 2010,36(6):1837-1844. DOI URL
[31]	MUKHOPADHYAY S, ANSAR S A, PAUL D, et al. Characteristics of refractory castablescontaining mullite and spinel coated graphites[J]. Materials and Manufacturing Processes, 2012,27(2):177-184. DOI URL
[32]	MUKHOPADHYAY S, PAUL D, BHOWMICK G, et al. Mullite coatings on graphite for application in carbon containing monolithic refractory[J]. Industrial Ceramics, 2011,31(2):129-136.
[33]	DUTTA S, DAS P, DAS A, et al. Significant improvement of refractoriness of Al₂O₃-C castables containing calcium aluminate nano-coatings on graphite[J]. Ceramics International, 2014,40(3):4407-4414. DOI URL
[34]	MUKHOPADHYAY S, DAS G, BISWAS I. Nanostructured cementitious sol-gel coating on graphite for application in monolithic refractory composites[J]. Ceramics International, 2012,38(2):1717-1724. DOI URL
[35]	MUKHOPADHYAY S, DUTTA S. Comparison of solid state and sol-gel derived calcium aluminate coated graphite and characterization of prepared refractory composite[J]. Ceramics International, 2012,38(6):4997-5006. DOI URL
[36]	MUKHOPADHYAY S. Nanoscale calcium aluminate coated graphite for improved performance of alumina based monolithic refractory composite[J]. Materials Research Bulletin, 2013,48(7):2583-2588. DOI URL
[37]	MUKHOPADHYAY S, MONDAL C, CHAKRABORTY A, et al. In depth studies on cementitious nanocoatings on graphite for its contribution in corrosion resistance of alumina based refractory composite[J]. Ceramics International, 2015,41(9):11999-12010. DOI URL
[38]	HUANG J F, DENG F, CAO L Y, et al. Influence of infiltration additives on the phase Influence of infiltration additives on the phase,microstructure and oxidation resistance of SiC coating for graphite materials[J]. Key Engineering Materials, 2007, 336-338:1756-1758. DOI URL
[39]	ALIAKBARPOUR S, ZAKERI M, RAHIMIPOUR M R, et al. Effect of SiC-mullite coatings on oxidation resistance of graphite[J]. Advances in Applied Ceramics, 2014,113(6):358-361. DOI URL
[40]	MASOUDIFAR S, BAVAND-VANDCHALI M, GOLESTANI-FARD F, et al. Molten salt synjournal of a SiC coating on graphite flakes for application in refractory castables[J]. Ceramics International, 2016,42(10):11951-11957. DOI URL
[41]	YE J K, ZHANG S W, LEE W E. Molten salt synjournal and characterization of SiC coated carbon black particles for refractory castable applications[J]. Journal of the European Ceramic Society, 2013,33(10):2023-2029. DOI URL
[42]	YE J K, ZHANG S W, LEE W E. Novel low temperature synjournal and characterisation of hollow silicon carbide spheres[J]. Microporous and Mesoporous Materials, 2012,152:25-30. DOI URL
[43]	DING J, DENG C J, YUAN W J, et al. Novel synjournal and characterization of silicon carbide nanowires on graphite flakes[J]. Ceramics International, 2014,40(3):4001-4007. DOI URL
[44]	ZHANG S W, LEE W E. Carbon containing castables:current status and future prospects[J]. British Ceramic Transactions, 2002,101(1):1-8. DOI URL
[45]	LIU X G, WANG Z F, ZHANG S W. Molten salt synjournal and characterization of titanium carbide-coated graphite flakes for refractory castable applications[J]. International Journal of Applied Ceramic Technology, 2011,8(4):911-919. DOI URL
[46]	LIU X, ZHANG S W. Low-temperature preparation of titanium carbide coatings on graphite flakes from molten salts[J]. Journal of the American Ceramic Society, 2008,91(2):667-670. DOI URL
[47]	丁军, 邓承继, 张小军, 等. 熔盐介质中石墨表面碳化钛包覆的研究[J]. 功能材料, 2014,45(3):66-69.
[48]	YE J K. Preparation and characterisation of novel carbon materials for refractory castable applications[D]. Sheffield:University of Sheffield, 2014.
[49]	LEE W E, ZHANG SW. Melt corrosion of oxide and oxide-carbon refractories[J]. International Materials Reviews, 1999,44(3):77-104. DOI URL
[50]	ZOU Y, GU H Z, HUANG A, et al. Effects of MgO micropowder on microstructure and resistance coefficient of Al₂O₃-MgO castable matrix[J]. Ceramics International, 2014,40(5):7023-7028. DOI URL
[51]	江泓. Al₂O₃-SiC-C出铁沟浇注料抗氧化性能提高的新进展[J]. 江苏陶瓷, 2005,38(6):7-11.
[52]	李赛赛, 王军凯, 段红娟, 等. 水热碳化制备碳微球及其在Al₂O₃-SiC-C浇注料中的应用[J]. 硅酸盐学报, 2018,46(3):341-346.
[53]	LI S S, LIU J H, WANG J K, et al. Fabrication of graphitic carbon spheres and their application in Al₂O₃-SiC-C refractory castables[J]. International Journal of Applied Ceramic Technology, 2018,15(5):1166-1181. DOI URL
[54]	LI S S, LIU J H, WANG J K, et al. Catalytic preparation of graphitic carbon spheres for Al₂O₃-SiC-C castables[J]. Ceramics International, 2018,44(11):12940-12947. DOI URL
[55]	熊鑫. 石墨烯/氧化铝复合粉体的制备及其在浇注料中的应用[D]. 武汉:武汉科技大学, 2013.
[56]	肖国庆, 石佳佳, 丁冬海. 含碳铝酸钙粉体的燃烧合成及其微观表征[J]. 硅酸盐学报, 2018,46(6):829-936.
[57]	石佳佳. 燃烧合成制备含碳铝酸钙粉体及其机理研究[D]. 西安:西安建筑科技大学, 2018.
[58]	李盼盼, 肖国庆, 丁冬海, 等. 烧结法制备炭黑/铝酸钙水泥及其结合耐火浇注料的性能[J]. 硅酸盐学报, 2019,47(3):403-411.
[59]	雷紫涵, 肖国庆, 丁冬海, 等. 埋碳烧结法制备碳/铝酸钙复合粉体及其微观表征[J]. 材料导报, 2018,32(22):3862-3867.
[60]	XIAO G Q, YANG S L, DING D H, et al. One-step synjournal of in-situ carbon-containing calcium aluminate cement as binders for refractory castables[J]. Ceramics International, 2018(44):15378-15384.
[61]	DING D H, YANG S L, XIAO G Q, et al. One-step synjournal of in-situ nanocarbon-containing calcium aluminate cement in reducing atmosphere[J]. International Journal of Applied Ceramic Technology, 2019,16(4):1416-1424 DOI URL
[62]	DING D H, YANG S L, XIAO G Q, et al. Investigation on the properties of Al₂O₃-MgO refractory castables bonded by in-situ carbon-containing calcium aluminate cement[J]. Materials Research Express, 2018,5(9):1-9.
[63]	YANG S L, XIAO G Q, DING D H, et al. Improved corrosion resistance of Al₂O₃-SiC-C castables through in situ carbon containing aluminate cement as binder[J]. International Journal of Applied Ceramic Technology, 2020,17(3):1044-1051. DOI URL
[64]	YANG S L, XIAO G Q, DING D H, et al. Effect of in-situ carbon containing calcium aluminate cement on properties of Al₂O₃-SiC-C based trough castables[J]. Journal of Asian Ceramic Societies, 2020,8(1):162-169. DOI URL

含碳耐火浇注料的研究现状

Research status of carbon-containing refractory castables

RichHTML

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献 64

相关文章 15

编辑推荐

Metrics

本文评价

[1]	李莹, 汪涤, 赵莉, 尹艺程, 贾全利. 石墨类型对Al₂O₃-MgO浇注料性能的影响[J]. 耐火材料, 2024, 58(4): 323-328.
[2]	何维祥, 罗明, 何亮, 柯极峰. 高精炼比模式下钢包渣线镁碳砖的研制及应用[J]. 耐火材料, 2024, 58(3): 234-237.
[3]	孟红涛, 马龙斌, 刘鑫. 预氧化对焦炉用氮化物结合碳化硅材料抗氧化性的影响[J]. 耐火材料, 2024, 58(3): 242-245.
[4]	邹鑫, 肖学平, 宋雅楠, 陈平安, 朱颖丽, 李享成. B₄C添加量对Al₂O₃-C材料性能的影响[J]. 耐火材料, 2023, 57(4): 310-313.
[5]	吕思维, 李明晖, 倪薇, 童胜利, 陈若愚, 李赛赛, 李灿华. 锂辉石粒度对Al₂O₃-SiC-C浇注料性能的影响[J]. 耐火材料, 2023, 57(4): 337-342.
[6]	龙图, 顾华志, 张美杰, 黄奥, 邱文冬. 钛铁渣加入量对Al₂O₃-SiC-C铁沟浇注料性能的影响[J]. 耐火材料, 2023, 57(4): 351-355.
[7]	贺远航, 钱凡, 郭海荣, 李化龙, 路跃, 刘国齐, 李红霞. h-BN在耐火材料和冶金用高温陶瓷中的应用进展[J]. 耐火材料, 2023, 57(4): 360-364.
[8]	周瑞琪, 范慧琳, 王智明, 蔡伟杰, 段红娟, 张海军. 水热法制备氢氧化镁改性鳞片石墨[J]. 耐火材料, 2023, 57(2): 117-120.
[9]	牛世程, 吴吉光, 梁鹏鹏, 相宇博, 郑翰, 卜相娟, 罗天. BN微粉加入量对Si₃N₄-BN复合材料高温抗氧化性的影响[J]. 耐火材料, 2022, 56(6): 495-498.
[10]	曹济源, 马北越, 王露露, 李广明, 刘永利, 宋娜, 田剑. Al₂O₃、SiO₂质量比对Al₂O₃-SiO₂-MgO复合粉体电绝缘性能的影响[J]. 耐火材料, 2022, 56(5): 396-399.
[11]	蔡伟杰, 李亚格, 张鑫, 郭俊艳, 段红娟, 张海军. 鳞片石墨表面改性研究进展[J]. 耐火材料, 2022, 56(5): 447-451.
[12]	王佳平, 朱冲, 吴吉光, 黄志刚, 吕春江. 几种碳化硅耐火材料在高温水蒸气中的抗氧化性能比较[J]. 耐火材料, 2022, 56(4): 351-355.
[13]	蔡伏玲, 韩兵强, 陈俊峰, 苗正, 王义龙. 添加Ti₃AlC₂对MgO-C材料性能的影响[J]. 耐火材料, 2022, 56(3): 193-196.
[14]	付云鹤, 夏春玲, 牛峥, 穆元冬, 郝占宏, 叶国田. 低掺量红柱石粉对Al₂O₃-SiC-C浇注料性能的影响[J]. 耐火材料, 2022, 56(3): 210-213.
[15]	段红娟, 蔡伟杰, 张浩, 李发亮, 张海军. 水热法制备碱式硫酸镁/氢氧化镁改性膨胀石墨[J]. 耐火材料, 2021, 55(6): 461-465.