纳米TiO2加入量对镁钙砂性能的影响

doi:10.3969/j.issn.1001-1935.2025.01.008

耐火材料 ›› 2025, Vol. 59 ›› Issue (1): 45-49.DOI: 10.3969/j.issn.1001-1935.2025.01.008

纳米TiO₂加入量对镁钙砂性能的影响

臧伟楠, 栾舰, 王春艳, 李佳, 韩昊鹏

辽宁科技大学材料与冶金学院辽宁鞍山 114051

收稿日期:2024-05-11 出版日期:2025-02-15 发布日期:2025-02-27
通讯作者: 栾舰,男,1971年生,硕士,副教授。E-mail:Jianluan@126.com
作者简介:臧伟楠:男,1997年生,硕士研究生。E-mail:867279774@qq.com
基金资助:
* 辽宁省教育厅一般项目(LJKFZ20220196)。

Influence of nano TiO₂ addition on properties of magnesia-calcia clinkers

Zang Weinan, Luan Jian, Wang Chun-yan, Li Jia, Han Haopeng

First author’s address:School of Materials and Metallurgy,University of Science and Technology Liaoning,Anshan 114051,Liaoning,China

Received:2024-05-11 Online:2025-02-15 Published:2025-02-27

摘要/Abstract

摘要： 为了改善镁钙材料的抗水化性能并进一步提高其他性能,以白云石粉和轻烧镁粉为主要原料,外加纳米TiO₂,以酚醛树脂为结合剂,在100 MPa下成型,经1 650 ℃煅烧3 h制成镁钙砂试样,研究了TiO₂外加量(外加质量分数分别为0、2%、4%、6%和8%)对其性能的影响。结果表明:纳米TiO₂的引入可使材料内产生固溶体,促进晶粒长大,同时材料内会有新相CaTiO₃和Ca₄Ti₃O₁₀生成,提高颗粒间结合程度,但过量的新相生成会阻碍材料内气体排出,影响烧结过程。随着纳米TiO₂外加量的增加,试样中CaTiO₃和Ca₄Ti₃O₁₀的含量增加,体积密度逐渐降低,显气孔率逐渐增大,常温抗折强度、常温耐压强度和抗水化性能以及热震后的常温抗折强度先增大后减小。当纳米TiO₂外加量为2%(w)时,试样的强度、抗热震性和抗水化性能最高。

关键词: 镁钙材料, 纳米TiO₂, 力学性能, 抗水化性

Abstract: In order to improve the hydration resistance of magnesia-calcia materials and further enhance other properties,magnesia-calcia clinker samples were prepared using dolomite powder and light-burned magnesia powder as the main raw materials,phenolic resin as the binder,extra adding nano TiO₂,molding at 100 MPa,and calcining at 1 650 ℃ for 3 h.Effect of TiO₂ additions (0,2%,4%,6%,and 8%,by mass) on the properties of the samples was investigated.The results show that the introduction of nano TiO₂ can generate solid solution in the materials and promote grains growth,while new phases CaTiO₃ and Ca₄Ti₃O₁₀ are generated to improve the bonding degree of particles;but the excessive generation of the new phases will hinder the gas discharge in the materials and affect the sintering process.With the increase of the nano TiO₂ addition,the content of CaTiO₃ and Ca₄Ti₃O₁₀ in the samples increases,the bulk density decreases gradually,the apparent porosity increases,and the cold modulus of rupture,the cold crushing strength and the hydration resistance,as well as the cold modulus of rupture after thermal shock firstly increase and then decrease.The strength,the thermal shock resistance and the hydration resistance of the samples are the highest when the nano TiO₂ addition is 2%.

Key words: magnesia-calcia materials, nano TiO₂, mechanical property, hydration resistance

中图分类号:

TQ175

臧伟楠, 栾舰, 王春艳, 李佳, 韩昊鹏. 纳米TiO₂加入量对镁钙砂性能的影响[J]. 耐火材料, 2025, 59(1): 45-49.

Zang Weinan, Luan Jian, Wang Chun-yan, Li Jia, Han Haopeng. Influence of nano TiO₂ addition on properties of magnesia-calcia clinkers[J]. Refractories, 2025, 59(1): 45-49.

参考文献

[1] 王雪瑶,姜凡,刘长春.镁钙系耐火材料的发展研究[J].陶瓷,2008(2):33-34.
[2] 王宏联,崔庆阳,薛群虎,等.MgO-CaO耐火材料性能研究进展[J].耐火材料,2010,44(1):67-70+74.
[3] 史宏硕.镁钙质耐火材料的使用现状与发展[J].智慧中国,2022(8):46-47.
[4] 魏明坤,曾利红,刘丽君.镁钙系耐火材料的研究进展[J].材料与冶金学报,2005,4(3):201-205.
[5] 吴占德,蒋明学.镁钙系耐火材料的研究现状[J].耐火材料,2009,43(2):136-139.
[6] GHASEMI-KAHRIZSANGI S,NEMATI A,SHAHRIKI A,et al.Effect of nano-sized Fe₂O₃ on microstructure and hydration resistance of MgO-CaO refractories[J].International Journal of NanoScience and Nanotechnology,2016,12:19-26.
[7] DEHSHEISH H G,KARAMIAN E,OWSALOU R G,et al.Improvement in performance of MgO-CaO refractory composites by addition of Iron (III) oxide nanoparticles[J].Ceramics International,2018,44(13):15880-15886.
[8] SHAHRAKI A,GHASEMI-KAHRIZSANGI S,NEMATI A.Performance improvement of MgO-CaO refractories by the addition of nano-sized Al₂O₃[J].Materials Chemistry and Physics,2017,198:354-359.
[9] GHASEMI-KAHRIZSANGI S,DEHSHEISH H G,BOROUJERDNIA M.MgO-CaO-Cr₂O₃ composition as a novel refractory brick: Use of Cr₂O₃ nanoparticles[J].Boletín de la Sociedad Española de Cerámica y Vidrio,2017,56(2):83-89.
[10] GHASEMI-KAHRIZSANGI S,SHAHRIKI A,FAROOGHI M.Effect of nano-TiO₂ additions on the densification and properties of magnesite-dolomite ceramic composites[J].Iranian Journal of Science and Technology,Transaction A:Science,2018,42(2):567-575.
[11] GHASEMI-KAHRIZSANGI S,SEDEH M B,DEHSHEISH H G,et al.Densification and properties of ZrO₂ nanoparticles added magnesia-doloma refractories[J].Ceramics International,2016,42(14):15658-15663.
[12] GHASEMI-KAHRIZSANGI S,DEHSHEISH H G,BOROUJERDNIA M.The effect of nano meter size ZrO₂ particles addition on the densification and hydration resistance of magnesite-dolomite refractories[J].Iranian Journal of Materials Science and Engineering,2016,13(4):33-40.
[13] CHEN M,LU C Y,YU J K.Improvement in performance of MgO-CaO refractories by addition of nano-sized ZrO₂[J].Journal of the European Ceramic Society,2007,27(16):4633-4638.
[14] GHASEMI-KAHRIZSANGI S,DEHSHEISH H G,KARAMIAN E.Effect of MgAl₂O₄ nanoparticles addition on the densification and properties of MgO-CaO refractories[J].Ceramics International,2017,43(6):5014-5019.
[15] MOHAMMADIHOOYHE M,KARAMIAN E,EMADI R.The impact of MgAl₂O₄ nano-particles on the hydration-resistance improvement of dolomite-based refractories[J].Ceramics International,2019,45(16):20674-20677.
[16] MOHAMMADIHOOYHE M,KARAMIAN E,EMADI R.Effect of magnesium-aluminate spinel nano-particles on microstructure and properties behaviors of doloma-containing refractories[J].Ceramics International,2020,46(2):1662-1667.

纳米TiO₂加入量对镁钙砂性能的影响

Influence of nano TiO₂ addition on properties of magnesia-calcia clinkers

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	黄科, 殷超凡, 王黎, 于仁红, 董宾宾臧云飞, 梁艳晨, 李满仓, 秦峰. 中空骨料对轻质MgO-MgAl₂O₄-C耐火材料力学性能的影响[J]. 耐火材料, 2025, 59(1): 38-44.
[2]	张瑞, 孙旭东, 魏瀚, 袁彪, 王俊涛袁林, 刘士范, 陈松林. 65~69工艺参数对Al₂O₃-C耐火材料抗氧化性和抗水化性的影响[J]. 耐火材料, 2025, 59(1): 65-69.
[3]	刘苗伟, 贾全利, 彭西高, 张小会, 张子英, 王海梅, 王佳. 硼/碳热还原结合热压烧结原位制备ZrB₂陶瓷及其性能研究[J]. 耐火材料, 2024, 58(5): 381-386.
[4]	张晓存, 聂建华, 梁永和, 高东升, 鄢文, 尹玉成. 菱镁矿尾矿细粉对MgO-SiO₂质浇注料性能的影响[J]. 耐火材料, 2024, 58(5): 387-392.
[5]	李文凤, 申天姿, 郭会师, 曹金金, 康晓旭, 石凯, 康晓阳. 多羟基糖类结合剂对Al₂O₃-SiC-C质无水炮泥性能的影响[J]. 耐火材料, 2024, 58(4): 314-318.
[6]	贾换, 冯需, 袁蝴蝶. Ti₃SiC₂基复合材料的研究进展[J]. 耐火材料, 2024, 58(4): 362-368.
[7]	邓承继, 贺锋, 梁一鸣, 李季, 高超, 慕孟. TiO₂添加量对SiC多孔陶瓷物相组成及性能的影响[J]. 耐火材料, 2024, 58(2): 93-98.
[8]	闵昌胜, 董博, 余超, 邓承继, 邢广超, 丁军, 刘浩, 祝洪喜. 颗粒级配对重结晶SiC蜂窝陶瓷显微结构与力学性能的影响[J]. 耐火材料, 2024, 58(2): 127-131.
[9]	王永新, 高亚博, 方要华, 李亚格, 黄仲, 张海军. 耐火浇注料用SiO₂、Al₂O₃和MgO微粉结合剂研究进展[J]. 耐火材料, 2024, 58(2): 167-173.
[10]	薛天雨, 黄仲, 黄忍, 张海军. 改性轻烧氧化镁细粉的抗水化性能[J]. 耐火材料, 2024, 58(1): 30-34.
[11]	夏玉婷, 杨文博, 饶羽彤, 聂锐杉, 姚远. 轻质高强莫来石浇注料的组分优化和性能增强[J]. 耐火材料, 2024, 58(1): 72-75.
[12]	姚万凯, 方斌祥, 李享成, 陈平安, 朱颖丽, 朱伯铨. 碳化硼复合陶瓷增强增韧研究进展[J]. 耐火材料, 2023, 57(6): 531-537.
[13]	余超, 杨昕雨, 陈博, 邓承继, 吕治江, 董博陈嵛沣, 丁军, 祝洪喜. 石灰岩尾矿制备多孔陶瓷及其性能研究[J]. 耐火材料, 2023, 57(4): 281-285.
[14]	邝昌柳, 王杏, 刘正龙, 丁军, 余超, 邓承继, 祝洪喜. ZrC改性石墨对低碳Al₂O₃-C耐火材料结构与性能的影响[J]. 耐火材料, 2023, 57(4): 295-299.
[15]	邹鑫, 肖学平, 宋雅楠, 陈平安, 朱颖丽, 李享成. B₄C添加量对Al₂O₃-C材料性能的影响[J]. 耐火材料, 2023, 57(4): 310-313.