Refractories ›› 2022, Vol. 56 ›› Issue (6): 548-552.DOI: 10.3969/j.issn.1001-1935.2022.06.020

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Effect of sintering aids on thermal conductivity of Si3N4 ceramics

Guo Hongli, Yao Can, Cheng Benjun, Gu Qiang   

  1. Sinosteel Luoyang Institute of Refractories Research Co.,Ltd.,Luoyang 471039,Henan,China
  • Received:2022-01-11 Online:2022-12-15 Published:2022-12-26

烧结助剂对Si3N4陶瓷导热性能影响的研究现状

郭红丽1), 姚灿2), 程本军2), 顾强1)   

  1. 1)中钢集团洛阳耐火材料研究院有限公司 河南洛阳 471039
    2)中南大学 能源科学与工程学院 湖南长沙 410083
  • 作者简介:郭红丽:女,1973年生,硕士,高级工程师。E-mail:1164567257@qq.com

Abstract: The effects of single,binary and ternary sintering aids on the thermal conductivity of Si3N4 ceramics were reviewed.The comprehensive analysis shows that the introduction of sintering aids can reduce the sintering temperature of Si3N4 ceramics,increase the density,and reduce the glass phase and oxygen contents,so that the Si3N4 grains grow up and contact more closely,thus effectively improving the thermal conductivity of Si3N4 ceramics.The binary sintering aids have the greatest influence on the thermal conductivity,and Si3N4 ceramics with high thermal conductivity can be obtained by appropriately adjusting the sintering aids addition or the ratio of sintering aids.

Key words: silicon nitride ceramics, sintering aids, thermal conductivity, density

摘要: 综述了一元烧结助剂、二元烧结助剂和三元烧结助剂对Si3N4陶瓷导热性能的影响。通过综合分析可知:烧结助剂的引入可降低Si3N4陶瓷的烧结温度,提高Si3N4陶瓷的致密度;也可降低Si3N4陶瓷中玻璃相和氧含量,从而使Si3N4晶粒长大,使晶粒接触更加紧密。进而有效改善Si3N4陶瓷的导热性能。其中,二元烧结助剂对Si3N4陶瓷导热性能影响最大,通过适量调整烧结助剂的含量或烧结助剂间的比例可得到热导率较高的Si3N4陶瓷。

关键词: Si3N4陶瓷, 烧结助剂, 热导率, 致密度

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