Refractories ›› 2021, Vol. 55 ›› Issue (4): 354-359.DOI: 10.3969/j.issn.1001-1935.2021.04.018

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Research progress on slag corrosion resistance of oxide-based refractories

Gao Jinghong1)(), Shi Yuchen1), Yu Guangsuo1,2), Su Weiguang1)(), Li Yao3), Zhang Junxian3)   

  1. 1)State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering,College of Chemistry and Chemical Engineering,Ningxia University,Yinchuan 750021,Ningxia,China
  • Received:2020-10-08 Online:2021-08-15 Published:2021-08-22
  • Contact: Su Weiguang

氧化物基耐火材料抗熔渣侵蚀研究进展

高靖红1)(), 史雨晨1), 于广锁1,2), 苏暐光1)(), 李耀3), 张俊先3)   

  1. 1)宁夏大学化学化工学院 省部共建煤炭高效利用与绿色化工国家重点实验室 宁夏银川 750021
    2)华东理工大学 洁净煤技术研究所 上海 200237
    3)山东兖矿国拓科技工程股份有限公司 山东济宁 273500
  • 通讯作者: 苏暐光
  • 作者简介:高靖红:女,1996年生,硕士研究生。E-mail: gjh126998@163.com
  • 基金资助:
    宁夏重大研发计划资助项目(2019BCH01001);宁夏重点研发计划资助项目(2019BDE03003)

Abstract:

Oxide-based refractories are widely used in high temperature industrial equipment fields such as ceramic manufacturing,petroleum and energy due to their excellent high temperature mechanical properties,good thermal shock stability and slag corrosion resistance.But slag penetration and chemical corrosion are the main factors leading to their destroy.The corrosion and penetration mechanisms of molten slag to single-phase oxides,multi-phase oxides and oxide-carbon composite refractories were reviewed.The changes in the properties and microstructure of refractories after corrosion were also analyzed.The future research direction of oxide-based refractories against corrosion by molten slag was prospected.

Key words: oxide, refractories, slag corrosion, penetration, damage

摘要:

氧化物基耐火材料因其具备优异的高温力学性能、良好的抗热震性以及抗熔渣侵蚀性等优点,被广泛应用于陶瓷制造、石油和能源等高温工业装备领域,但熔渣渗透和化学侵蚀是导致其损毁的主要因素。综述了熔渣对单相氧化物、多相氧化物和氧化物-碳复合耐火材料的侵蚀和渗透机制,并对侵蚀后耐火材料性能的变化规律和显微结构的变化特征进行了分析。展望了氧化物基耐火材料抗熔渣侵蚀的研究方向。

关键词: 氧化物, 耐火材料, 抗熔渣侵蚀, 渗透, 损毁

CLC Number: